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Effect of Sulfur or Nitrogen Poisoning on the Activity and Selectivity of Y-Zeolite-Supported Pt–Pd Catalysts in the Hydrogenation of Tetralin

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Abstract

The effects of dibenzothiophene or quinoline poisoning on the activity and selectivity of Y-zeolite-supported Pt–Pd catalysts, in the hydrogenation of tetralin at 523 K and 70 bar initial pressure, were studied in a high pressure batch reactor as a function of composition. It was found that both poisons influenced, in very similar ways, the patterns of tolerance to poisons and of cis/trans selectivity vs. catalyst composition.

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Authors and Affiliations

  1. Dept. de Físico-Química, Instituto de Química, Universidade Federal do Rio de Janeiro, Ilha do Fundão, Centro de Tecnologia, Bl. A, Rio de Janeiro, RJ 21949-900, Brazil

    Carla Cristina Costa Augusto & Arnaldo da Costa Faro Jr.

  2. PETROBRAS/CENPES/DITEP, Ilha do Fundão, Q. 7, Rio de Janeiro, RJ 21949-900, Brazil

    José Luiz Zotin

Authors
  1. Carla Cristina Costa Augusto
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  2. José Luiz Zotin
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  3. Arnaldo da Costa Faro Jr.
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Augusto, C.C.C., Zotin, J.L. & Faro, A.d.C. Effect of Sulfur or Nitrogen Poisoning on the Activity and Selectivity of Y-Zeolite-Supported Pt–Pd Catalysts in the Hydrogenation of Tetralin. Catalysis Letters 75, 37–43 (2001). https://doi.org/10.1023/A:1016636302112

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