Abstract
The present work reports the effect of metal particle size on the selectivity to crotyl alcohol (SUOL) in the liquid phase hydrogenation of crotonaldehyde over SiO2 and a-Al2O3-supported Pt and Pt-Sn catalysts. It was demonstrated that, for the monometallic catalysts, a higher particle size led to a higher SUOL, while for the bimetallic catalysts, this effect was not so important.
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Santori, G.F., Casella, M.L., Siri, G.J. et al. Effect of particle size in the hydrogenation of crotonaldehyde on supported Pt and Pt-Sn catalysts. Reaction Kinetics and Catalysis Letters 75, 225–230 (2002). https://doi.org/10.1023/A:1015234526107
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DOI: https://doi.org/10.1023/A:1015234526107