Abstract
The reactions of [Fe(t-BuNC)3(CO)2] with HgX2 (X= Cl, Br or I) give two different types of iron-mercury halide complex, depending on the molar ratio of reactants used. An equimolar ratio of the reactants produces the neutral adducts [Fe(t- BuNC)3(CO)2(HgX2)],whereas two equivalents of HgX2 generate the electrolytes [Fe(t- BuNC)3(CO)2(HgX)]HgX3. The Mössbauer, i.r. data, and conductivity measurements of these complexes are presented and discussed in terms of their chemical structures and bonding.
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Morigaki, M.K., Machado, L.C., da Silva, E.M. et al. Preparation and Mössbauer studies of iron-mercury mixed isocyanide-carbonyl complexes. Transition Metal Chemistry 24, 5–7 (1999). https://doi.org/10.1023/A:1006924105568
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DOI: https://doi.org/10.1023/A:1006924105568