Skip to main content
SpringerLink
Log in

Kinetic Analysis of the Mechanism of Oxidation of CO on Co/ZSM-5

  • Published:
Theoretical and Experimental Chemistry Aims and scope

Abstract

We have studied the kinetic behavior of oxidation of carbon monoxide on Co-containing zeolite ZSM-5. We have shown that the kinetic curves obtained for the dependence of the reaction rate on the reagent concentration can be described by an Eley–Rideal mechanism, which assumes that oxygen can be adsorbed on the surface of the catalyst in both atomic and molecular form, followed by reaction of CO from the gas phase with the adsorbed oxygen.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

REFERENCES

  1. M. Anpo, M. Matsuoka, Y. Shioya, et al., J. Phys. Chem., 98, 5744 (1994).

    Google Scholar 

  2. A. V. Kucherov, A. A. Slinkin, S. S. Goryashenko, and K. J. Slovetskaya, J. Catal., 118, No. 3, 459 (1989).

    Google Scholar 

  3. N. V. Nekrasov, A. A. Slinkin, A. V. Kucherov, et al., Kinet. Katal., 38, No. 1, 90-93 (1997).

    Google Scholar 

  4. M. F. Savchits, V. Z. Radkevich, E. Ya. Ustilolvskaya, et al., React. Kinet. Catal. Lett., 52, No. 1, 43-49 (1994).

    Google Scholar 

  5. A. V. Kucherov, T. N. Kucherova, V. D. Nissenbaum, and A. A. Slinkin, Kinet. Katal., 36, No. 5, 731-735 (1995).

    Google Scholar 

  6. V. K. Yatsimirskii, L. P. Oleksenko, and L. V. Lutsenko, Ukr. Khim. Zh., 69, No. 8, 94-99 (2003).

    Google Scholar 

  7. G. I. Golodets, Heterogeneous Catalytic Reactions with Participation of Molecular Oxygen [in Russian], Naukova Dumka, Kiev (1977).

    Google Scholar 

  8. G. S. Yablonskii, V. I. Bykov, and A. N. Gorban', Kinetic Models of Catalytic Reactions [in Russian], Nauka, Novosibirsk (1983).

    Google Scholar 

  9. Yu. I. Pyatnitskii and V. M. Vorotyntsev, Teor. Éksp. Khim., 20, No. 2, 238-241 (1984).

    Google Scholar 

  10. N. I. Il'chenko and A. V. Fesenko, Katal. Katalizat., 19, 54-57 (1981).

    Google Scholar 

  11. V. K. Yatsimirskii, O. Yu. Boldyreva, and L. P. Oleksenko, Teor. Éksp. Khim., 37, No. 6, 357-362 (2001).

    Google Scholar 

  12. Yu. I. Pyatnitskii, N. V. Pavlenko, and N. I. Il.chenko, Introduction to Nonlinear Kinetics of Heterogeneous Catalysis [in Russian], Kvik-Print, Kiev (1998).

    Google Scholar 

  13. R. W. Maatman, J. Catal., 19, 64-73 (1970).

    Google Scholar 

  14. E. A. Moelwyn-Hughes, Physical Chemistry [Russian translation], Izdat. Inostr. Lit., Moscow (1962).

    Google Scholar 

  15. A. A. Davydov, IR Spectroscopy in the Surface Chemistry of Oxides [in Russian], Nauka, Novosibirsk (1984).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Taras Shevchenko Kyiv National University, 64 Volodymyrs'ka Vul., 01033, Kyiv, Ukraine

    V. K. Yatsimirskii, L. P. Oleksenko & L. V. Lutsenko

Authors
  1. V. K. Yatsimirskii
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. L. P. Oleksenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. L. V. Lutsenko
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Yatsimirskii, V.K., Oleksenko, L.P. & Lutsenko, L.V. Kinetic Analysis of the Mechanism of Oxidation of CO on Co/ZSM-5. Theoretical and Experimental Chemistry 40, 44–51 (2004). https://doi.org/10.1023/B:THEC.0000020765.21189.ec

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/B:THEC.0000020765.21189.ec

Search

Navigation