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Reaction of Arendiazonium Salts and SO2with α-Nitroolefins

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Abstract

In reaction of β-nitrostyrene and 2-(2-nitrovinyl)furan with arenediazonium chlorides and SO2 in the presence of copper(II) chloride products were obtained resulting from addition of arylsulfonyl group and a hydrogen atom across the C=C bond: 2-nitro-1-phenylethylsulfonylarenes and 2-(1-arylsulfonyl-2-nitroethyl)furans respectively. An anion-radical mechanism of the reaction was suggested.

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Bilaya, E.E., Obushak, N.D., Buchinskii, A.M. et al. Reaction of Arendiazonium Salts and SO2with α-Nitroolefins. Russian Journal of Organic Chemistry 40, 191–194 (2004). https://doi.org/10.1023/B:RUJO.0000034940.16955.8e

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  • DOI: https://doi.org/10.1023/B:RUJO.0000034940.16955.8e

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