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Linear Free Energy Relationships in SNAr Reactions of Aryl and Diaryl N-Anions with Aryl Halides

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Abstract

A good correlation has been established between the Brønsted coefficients βN u c and βo x for reactions of aryl-containing N-anions with various aryl halides. This correlation reflects the dependence of the internal barrier of aromatic nucleophilic substitution on the oxidation potentials of nucleophiles.

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  1. Vorozhtsov Institute of Organic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk, Russia

    V. M. Vlasov & I. A. Os'kina

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  1. V. M. Vlasov
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  2. I. A. Os'kina
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Vlasov, V.M., Os'kina, I.A. Linear Free Energy Relationships in SNAr Reactions of Aryl and Diaryl N-Anions with Aryl Halides. Russian Journal of General Chemistry 74, 600–605 (2004). https://doi.org/10.1023/B:RUGC.0000031864.05199.b2

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  • DOI: https://doi.org/10.1023/B:RUGC.0000031864.05199.b2

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