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(NH 4 )Zn 2 (PO 4 )(HPO 4 ): Hydrothermal Synthesis and Reaction with n-Alkylamine Vapours

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Abstract

(NH4)Zn2(PO4)(HPO4) was synthesized under mild hydrothermal conditions in the presence of urea. The reaction with n-alkylamines has been investigated by exposing the solid to amines vapor. The new materials were characterized by chemical and thermal analysis, powder X-ray diffraction, and IR spectroscopy. In addition, the simultaneous reaction of this compound with two or more n-alkylamine different molecules was investigated. The reaction of large n-alkylamine molecules was observed to be faster if there is a shorter alkyl chain amine acting as a catalyst, yielding on completion single amine materials. In the case of a vapor mixture of several amines, the compound obtained depends on the reaction time.

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References

  1. R.M. Barrer: Hydrothermal Chemistry of Zeolites, Academic Press, London (1982).

    Google Scholar 

  2. I. Girnus, M.M. Pohl, J. Richter-Mendau, M. Schneider, M. Noak, D. Venzke, and J. Caro: Adv. Mater. 7, 711 (1995).

    Google Scholar 

  3. T.E. Gier and G.D. Stucky: Nature 349, 508 (1991).

    Google Scholar 

  4. Y.J. Li and M.S. Whittingham: Solid State Ionics 63, 391 (1993).

  5. R.H. Jones, J. Chen, G. Sankar, and J.M. Thomas: In J. Weitkamp, H.G. Karge, H. Pfeifer, W. Holderich (eds.), Zeolites and Related Micropourous Materials, Elsevier, Amsterdam (1994).

    Google Scholar 

  6. L.M. Meyer, R.C. Haushalter, and J. Zubieta: J. Solid State Chem. 125, 200 (1996).

    Google Scholar 

  7. A.I. Bortun, L.N. Bortun, A. Clearfield, M.A. Villa-García, J.R. García, and J. Rodríguez: J. Mater. Res. 11, 2490 (1996).

    Google Scholar 

  8. P. Feng, X. Bu, and G.D. Stucky: J. Solid State Chem. 129, 328 (1997).

  9. Y. Zhang, R.C. Haushalter, and J. Zubieta: Inorg. Chim. Acta 260, 105 (1997).

    Google Scholar 

  10. A.I. Bortun, L.N. Bortun, and A. Clearfield: Solvent Extr. Ion Exch. 15, 305 (1997).

    Google Scholar 

  11. G. Palavit, C. Mercier, L. Montagne, M. Drache, and Y. Abe: J. Am. Ceram. Soc. 81, 1521 (1998)

    Google Scholar 

  12. A.I. Bortun, L.N. Bortun, A. Espina, J.R. García, and A. Clearfield: J. Mater. Chem. 7, 2525 (1997)..248

    Google Scholar 

  13. A.I. Bortun, L.N. Bortun, A. Clearfield, C. Trobajo, and J.R. García: Mater. Res. Bull. 33, 583 (1998).

    Google Scholar 

  14. A. Stein, M. Fendorg, T. Jarvie, K.T. Mueller, A.J. Benbesi, and T.E. Mallouk: Chem. Mater. 7, 304 (1995).

    Google Scholar 

  15. M.S. Whittingham, J.K. Li, J.D. Guo, and P. Zavalij: In J. Rouxel, M. Tournoux, R. Brec (eds.), Soft Chemistry Routes to New Materials, Trans. Tech. Publications Ltd., Nantes (1993).

    Google Scholar 

  16. R. Chen, P. Zavalij, and M.S. Whittingham: Chem. Mater. 8, 1275 (1996).

    Google Scholar 

  17. W. Liu, Y.L. Liu, Z. Shi, and W.Q. Pang: J. Mater. Chem. 10, 1451 (2000).

  18. P. Zhang, Y. Wang, G.S. Zhu, Z. Shi, Y.L. Liu, H.M. Yuan, and W.Q. Pang: J. Solid State Chem. 154, 368 (2000).

    Google Scholar 

  19. C.H. Lin and S.L. Wang: Chem. Mater. 12, 3617 (2000).

  20. J.H. Yu, Y. Wang, Z. Shi, and R.R. Xu: Chem. Mater. 13, 2972 (2001).

  21. R.I. Walton, A.J. Norquist, S. Neeraj, S. Natarajan, C.N.R. Rao, and O. O'Hare: Chem. Commun. 1990 (2001).

  22. R.C. Finn and J. Zubieta: J. Chem. Soc. Dalton Trans. 856 (2002).

  23. X. Bu, P. Feng, and G.D. Stucky: J. Solid State Chem. 125, 243 (1996).

  24. M. Wiebcke: J. Mater. Chem. 12, 143 (2002).

    Google Scholar 

  25. H.Y. Ng and W.T.A. Harrison: Microporous Mesoporous Mater. 50, 187 (2001).

    Google Scholar 

  26. S. Natarajan: Chem. Commun. 780 (2002).

  27. S. Neeraj, S. Natarajan, and C.N.R. Rao: Chem. Commun. 165 (1999).

  28. W.T.A. Harrison and L. Hannooman: Angew. Chem. Int. Ed. Engl. 36, 641 (1997).

    Google Scholar 

  29. W.T.A. Harrison and M.L.F. Phillips: Chem. Mater. 9, 1837 (1997).

    Google Scholar 

  30. W.T.A. Harrison and M.L.F. Phillips: Chem. Commun. 2771 (1996).

  31. S.L. Lawton: Science 247, 1319 (1990).

    Google Scholar 

  32. T.M. Nenoff, S.G. Thoma, P. Provencio, and R.S. Maxwell: Chem. Mater. 10, 3077 (1998).

    Google Scholar 

  33. Q. Huo, D.I. Margolese, U. Ciesla, P. Feng, T.E. Gier, P. Sieger, R. Leon, P.M. Petroff, F. Schüth, and G.D. Stucky: Nature. 368, 317 (1994).

    Google Scholar 

  34. Q. Huo, D.I. Margolese, U. Ciesla, D.G. Demuth, P. Feng, T.E. Gier, P. Sieger, A. Fironzi, B.F. Chmelka, F. Schüth, and G.D. Stucky: Chem Mater. 6, 1176 (1994).

    Google Scholar 

  35. C.G. Lugmai and T.D. Tilley: Inorg. Chem. 37, 6304 (1998).

  36. A. Clearfield and B.D. Roberts: Inorg. Chem. 27, 3237 (1988).

    Google Scholar 

  37. A. Espina, J.B. Parra, J.R. García, J.A. Pajares, and J. Rodríguez: J. Mater. Chem. Phys. 35, 250 (1993).

    Google Scholar 

  38. A. Menéndez, M. Bárcena, E. Jaimez, J.R. García, and J. Rodríguez: Chem. Mater. 5, 1078 (1993).

    Google Scholar 

  39. A. Espina, E. Jaimez, S.A. Khainakov, C. Trobajo, J.R. García, and J. Rodríguez: Chem. Mater. 10, 2490 (1998).

    Google Scholar 

  40. Z. Bircsak and W.T.A. Harrison: Acta Cryst. C54, 1383 (1998).

    Google Scholar 

  41. F. Kohlbeck and E. M. Hörl: J. Appl. Crystallogr. 11, 60 (1978).

    Google Scholar 

  42. R. Shirley, The CRYSFIRE System for Automatic Powder Indexing: User's Manual, Lattice Press, Guildford, Surrey, UK, (2000).

    Google Scholar 

  43. T. Bataille, P. Bénard-Rocherullé, and D. Louër: J. Solid State Chem. 62, 140 (1998).

    Google Scholar 

  44. M.T. Averbuch-Pouchot: J. Appl. Crystallogr. 7, 51 (1974).

    Google Scholar 

  45. H.F. McMurdie, M.C. Morris, E.H. Evans, B. Paretzkin, W. Wong-Ng, L. Ettlinger, and C.R. Hubbard: Powder Diffr. 1, 64 (1986). B.E. Robertson and C. Calvo: J. Solid State Chem. 1, 120 (1970).

    Google Scholar 

  46. F. Menéndez, A. Espina, C. Trobajo, and J. Rodríguez: Mater. Res. Bull. 25, 1531 (1990).

    Google Scholar 

  47. A.I. Kitaigorogsky: Molecular Crystals and Molecules, Academic Press, New York (1973).

    Google Scholar 

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Authors and Affiliations

  1. Departamento de Química Orgánica e Inorgánica, Universidad de Oviedo, 33006 Oviedo, Spain

    Beatriz Ramajo, Aránzazu Espina, Sergei A. Khainakov & José R. García

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  1. Beatriz Ramajo
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  2. Aránzazu Espina
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  3. Sergei A. Khainakov
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  4. José R. García
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Ramajo, B., Espina, A., Khainakov, S.A. et al. (NH 4 )Zn 2 (PO 4 )(HPO 4 ): Hydrothermal Synthesis and Reaction with n-Alkylamine Vapours. Journal of Inclusion Phenomena 49, 241–248 (2004). https://doi.org/10.1023/B:JIPH.0000048313.50112.53

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  • DOI: https://doi.org/10.1023/B:JIPH.0000048313.50112.53

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