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The Spectral Displacement Technique for Determining the Binding Constants of β-Cyclodextrin – Alkyltrimethylammonium Inclusion Complexes

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Abstract

A survey of the literature reveals that the spectroscopic displacement method, in which phenolphthalein is used as a competitive chromophore to determine binding constants of β-cyclodextrin with surfactants was successful in the case of homologous hydrocarbon and fluorocarbon anionic surfactants. We show here that this method can be applied also for homologous alkyltrimethylammonium bromides (with alkyl varying from octyl- to hexadecyl) under the condition that the concentration of the cationic surfactant is distinctly lower than the value of itscritical micelle concentration.

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Authors and Affiliations

  1. Faculty of Chemistry, Jagiellonian University, 30-060 Kraków, Ingardena 3, Poland

    Bożena Tutaj, Anna Kasprzyk & Jan Czapkiewicz

Authors
  1. Bożena Tutaj
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  2. Anna Kasprzyk
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  3. Jan Czapkiewicz
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Tutaj, B., Kasprzyk, A. & Czapkiewicz, J. The Spectral Displacement Technique for Determining the Binding Constants of β-Cyclodextrin – Alkyltrimethylammonium Inclusion Complexes. Journal of Inclusion Phenomena 47, 133–136 (2003). https://doi.org/10.1023/B:JIPH.0000011783.40427.56

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  • DOI: https://doi.org/10.1023/B:JIPH.0000011783.40427.56

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