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Influence of the Nature of meso-Substituents and Extra-Ligands on the Luminescence of Ytterbium in Complexes with Porphyrins

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Abstract

Complexes of ytterbium with various meso-tetrasubstituted porphyrins have been obtained and their spectral-luminescent properties have been investigated. It is shown that the quantum yield and the lifetime of 4f-luminescence of the ytterbium ion are higher in complexes with porphyrins that contain aromatic and heteroaromatic meso-substituents (as compared to n-alkyl ones) and also in complexes with the acetylacetonate ion as an extra-ligand.

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Authors and Affiliations

  1. A. V. Bogatskii Physicochemical Institute, National Academy of Sciences of Ukraine, 86 Lyustdorf Road, Odessa, 65080, Ukraine

    N. V. Rusakova & V. Yu. Korovin

  2. I. I. Mechnikov Odessa National University, Odessa, Ukraine

    Z. I. Zhilina, S. V. Vodzinskii & Yu. V. Ishkov

Authors
  1. N. V. Rusakova
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  2. V. Yu. Korovin
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  3. Z. I. Zhilina
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  4. S. V. Vodzinskii
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  5. Yu. V. Ishkov
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Correspondence to V. Yu. Korovin.

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Rusakova, N.V., Korovin, V.Y., Zhilina, Z.I. et al. Influence of the Nature of meso-Substituents and Extra-Ligands on the Luminescence of Ytterbium in Complexes with Porphyrins. Journal of Applied Spectroscopy 71, 506–511 (2004). https://doi.org/10.1023/B:JAPS.0000046290.53115.e0

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  • DOI: https://doi.org/10.1023/B:JAPS.0000046290.53115.e0

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