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Heterocyclic Derivatives of Fullerene C60. 1. Synthesis of New Fulleropyrazolines by the 1,3-Dipolar Cycloaddition of Nitrile Imines

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

New stable [6,6]-closed cycloadducts, fulleropyrazolines containing aryl, hetaryl, trifluoromethyl, and other substituents in the five-membered ring, have been obtained by the 1,3-dipolar cycloaddition of nitrile imines to C60. Two methods of generating nitrile imines in situ have been used, the dehydrohalogenation of the corresponding hydrazonoyl halides by the action of triethylamine and the thermal decomposition of 2,5-diaryltetrazoles.

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Authors and Affiliations

  1. Moscow M. V. Lomonosov State University, Moscow, 119234, Russia

    M. V. Reinov, M. A. Yurovskaya, D. V. Davydov & A. V. Streletskii

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  1. M. V. Reinov
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  2. M. A. Yurovskaya
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  3. D. V. Davydov
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  4. A. V. Streletskii
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Reinov, M.V., Yurovskaya, M.A., Davydov, D.V. et al. Heterocyclic Derivatives of Fullerene C60. 1. Synthesis of New Fulleropyrazolines by the 1,3-Dipolar Cycloaddition of Nitrile Imines. Chemistry of Heterocyclic Compounds 40, 188–193 (2004). https://doi.org/10.1023/B:COHC.0000027890.05668.07

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  • DOI: https://doi.org/10.1023/B:COHC.0000027890.05668.07

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