Abstract
We have developed catalysts for the gasification of biomass with much higher energy efficiency than the conventional methods (noncatalyst, dolomite, and commercial steam reforming Ni catalyst). In our investigation, the Rh/CeO2 gave high yields of syngas for cellulose gasification using a fluidized-bed reactor with batch feeding of cellulose. However, the catalyst was deactivated because of sintering of CeO2 during the reaction. To prevent the CeO2 sintering, we have further improved the catalyst and found that Rh/CeO2/SiO2 was quite stable for the gasification of cellulose. It was demonstrated that Rh/CeO2/SiO2 gave almost complete gasification of real biomass (wood powder) at 873 K. These results indicate that the combination of this kind of catalyst and fluidized-bed reactor can realize the energy-efficient biomass gasification.
Similar content being viewed by others
References
J. M. Ogden, Annu. Rev. Energy Environ. 24 (1999) 227.
M. A. Caballero, J. Corella, M. P. Aznar and J. Gil, Ind. Eng. Chem. Res. 39 (2000) 1143.
F. Miccio, O. Moersch, H. Spliethoff and K. R. G. Hein, Fuel 78 (1999) 1473.
C. Brage, Q. Yu, G. Chen and K. Sjostrom, Biomass Bioenergy 18 (2000) 87.
I. Narvaez, A. Orío, M. P. Aznar and J. Corella, Ind. Eng. Chem. Res. 35 (1996) 2110.
P. Vriesman, E. Heginuz and K. Sjostrom, Fuel 79 (2000) 1371.
C. D. Blasi, G. Signorelli and G. Portoricco, Ind. Eng. Chem. Res. 38 (1999) 2571.
J. Gil, M. P. Aznar, M. A. Caballero, E. Frances and J. Corella, Energy Fuels 11 (1997) 1109.
A. A. C. M. Beenackers, Renewable Energy 16 (1999) 1180.
F. Miccio, O. Moersch, H. Spliethoff and K. R. G. Hein, Fuel 78 (1999) 1473.
K. Maniatis and A. A. C. M. Beenackers, Biomass Bioenergy 18 (2000) 1.
N. Abatzoglou, N. Barker, P. Hasler and H. Knoef, Biomass Bioenergy 18 (2000) 5.
H. A. M. Knoef and H. J. Koele, Biomass Bioenergy 18 (2000) 55.
F. Engstrom, Biomass Bioenergy 15 (1998) 259.
D. N. Bangala, N. Abatzoglou, J.-P. Martin and E. Chornet, Ind. Eng. Chem. Res. 36 (1997) 4184.
A. Olivares, M. P. Aznar, M. A. Caballero, J. Gil, E. Frances and J. Corella, Ind. Eng. Chem. Res. 36 (1997) 5220.
L. Mudge, E. G. Baker and D. G. Mitchell, Investigations on Catalyzed Steam Gasification of Biomass. PNL-3695 (Pacific Northwest National Laboratory, Richland, WA, 1981).
C. Ekstrom, N. Lindman and R. Petterson, Catalytic conversion of tars, carbon black, and methane from pyrolysis/gasification of biomass, in Proceedings of the Fundamentals of Thermochemical Conversion of Biomass Conference, R. P. Overend, T. A. Milne and L. K. Mudge (eds) (Elsevier Applied Press, London, 1982) p. 601.
A. A. C. M. Beenackers and K. Maniatis, Gas cleaning in electricity production via gasification of biomass. Conclusions of the Workshop, in Advances in Thermochemical Biomass Conversion, A. V. Bridgwater (Ed.) (Blackie Academic Press, London, 1994) p. 540.
A. V. Bridgwater, Appl. Catal. 116 (1994) 5.
P. Simell, E. Kurkela and P. Ståhlberg, Formation and catalytic decomposition of tars from fluidized-bed gasification, in Advances in Thermochemical Biomass Conversion, A. V. Bridgwater (Ed.) (Blackie Academic Press, London, 1994) p. 265.
N. Abatzoglou, P. Legast, P. Delvaux, D. Bangala and E. Chornet, Gas conditioning technologies for biomass and waste gasification, in Proceedings of the Third Biomass Conference of the Americas, R. P. Overend and E. Chornet (eds) (Elsevier Science Ltd., Oxford, 1997) p. 599.
M. P. Aznar, J. Corella, J. Gil, A. Martin, M. A. Caballero, A. Olivares and P. Perez, Biomass gasification with steam and oxygen mixtures at pilot plant scale and catalytic gas upgrading, Part I, in Developments in Thermochemical Biomass Conversion, A. V. Bridgwater and D. G. B. Boocock (eds). (Blackie Academic and Professional, London, 1997) p. 1194.
T. A. Milne, N. Abatzoglou and R. J. Evans, Biomass Gasifier “Tars”: Their Nature, Formation, and Conversion, NREL/TP–570–25357 (National Renewable Energy Laboratory, Golden, Colorado, 1998).
M. A. Caballero, M. P. Aznar, J. Corella, J. Gil and J. A. Martin, in Proceedings of the Fourth Biomass Conference of the Americas, R. P. Overend and E. Chornet (eds) (Pergamon, Oxford, 1999) p. 979.
J. Corella, M. A. Caballero, M. P. Aznar and J. Gil, in Proceedings of the Fourth Biomass Conference of the Americas, R. P. Overend and E. Chornet (eds) (Pergamon, Oxford, 1999) p. 933.
D. Sutton, B. Kelleher and J. R. H. Ross, Fuel Process. Technol. 73 (2001) 155.
L. García, M. L. Salvador, J. Arauzo and R. Bilbao, Energy Fuels 13 (1999) 851.
L. García, M. L. Salvador, J. Arauzo and R. Bilbao, Fuel Process. Technol. 69 (2001) 157.
L. García, R. French, S. Czernik and E. Chornet, Appl. Catal., A: Gen 201 (2000) 225.
L. García, M. L. Salvador, J. Arauzo and R. Bilbao, Ind. Eng. Chem. Res. 37 (1998) 3812.
J. Arauzo, D. Radlein, J. Piskorz and D. S. Scott, Ind. Eng. Chem. Res. 36 (1997) 67.
J. Arauzo, D. Radlein, J. Piskorz and D. S. Scott, Energy Fuels 8 (1994) 1192.
C. Courson, E. Makaga, C. Petit and A. Kiennemann, Catal. Today 63 (2000) 427.
Y. Tanaka, T. Yamaguchi, K. Yamasaki, A. Ueno and Y. Kotera, Ind. Eng. Chem. Res. 23 (1984) 225.
J. Gil, M. A. Caballero, J. A. Martin, M.-P. Aznar and J. Corella, Ind. Eng. Chem. Res. 38 (1999) 4226.
S. Rapagna, N. Jand, A. Kiennemann and P. U. Foscolo, Biomass Bioenergy 19 (2000) 187.
E. G. Baker, L. K. Mudge and M. D. Brown, Ind. Eng. Chem. Res. 26 (1987) 1335.
E. G. Baker, L. K. Mudge and W. A. Wilcox, Catalysis of gas phase reactions in steam gasification of biomass, in Fundamentals of Thermochemical Biomass Conversion, R. P. Overend et al., (eds) (Elsevier Applied Science, London, 1985) p. 863.
M. Asadullah, K. Tomishige and K. Fujimoto, Catal. Commun. 2 (2001) 63.
M. Asadullah, K. Tomishige, K. Fujimoto and K., Ind. Eng. Chem. Res. 25 (2001) 5894.
M. Asadullah, S. Ito, K. Kunimori, M. Yamada and K. Tomishige, J. Catal. 208 (2002) 255.
M. Asadullah, S. Ito, K. Kunimori and K. Tomishige, Ind. Eng. Chem. Res. 41 (2002) 4567.
M. Asadullah, S. Ito, K. Kunimori, M. Yamada and K. Tomishige, Environ. Sci. Tech. 36 (2002) 4476.
K. Tomishige, M. Asadullah, S. Ito and K. Kunimori, Kagaku Kogaku Ronbunshu 28 (2002) 666.
K. Tomishige, T. Miyazawa, M. Asadullah, S. Ito and K. Kunimori, J. Jpn. Pet. Inst. 46 (2003) 67.
M. Asadullah, T. Miyazawa, S. Ito, K. Kunimori, M. Yamada and K. Tomishige, Green Chem. 4 (2002) 385.
M. Asadullah, T. Miyazawa, S. Ito, K. Kunimori and K. Tomishige, Appl. Catal., A: Gen, 246 (2003) 103.
K. Tomishige, Y. Matsuo, Y. Sekine and K. Fujimoto, Catal. Commun. 2 (2001) 11.
K. Tomishige, Y. Matsuo, Y. Yoshinaga, Y. Sekine, M. Asadullah and K. Fujimoto, Appl. Catal., A: Gen. 223 (2002) 225.
Y. Matsuo, Y. Yoshinaga, Y. Sekine, K. Tomishige and K. Fujimoto, Catal. Today 63 (2000) 439.
K. Tomishige, Y. Matsuo, Y. Yoshinaga, M. Asadullah, Y. Sekine and K. Fujimoto, ACS Symp. Ser. 809 (2002) 303.
K. Tomishige, Y. Chen and K. Fujimoto, J. Catal. 181 (1999) 91.
K. Tomishige and K. Fujimoto, Catal. Surv. from Jpn. 2 (1998) 3.
K. Tomishige and K. Fujimoto, J. Jpn. Pet. Inst. 44 (2001) 65.
Y. Himeno, K. Tomishige and K. Fujimoto, J. Jpn. Pet. Inst. 42 (1999) 252.
A. Trovarelli, Catal. Rev. 38 (1996) 439.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Tomishige, K., Asadullah, M. & Kunimori, K. Novel Catalysts for Gasification of Biomass with High Conversion Efficiency. Catalysis Surveys from Asia 7, 219–233 (2003). https://doi.org/10.1023/B:CATS.0000008162.69178.17
Issue Date:
DOI: https://doi.org/10.1023/B:CATS.0000008162.69178.17