Skip to main content
SpringerLink
Log in

Hydrolytic condensation of trialkoxysilanes in the presence of alkali metal and copper(ii) ions. Influence of the reaction conditions on the structure of Cu/M organosiloxanes

  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

The formation of polyhedral copper/sodium(potassium) organosiloxanes was examined as a result of hydrolytic condensation of organotrialkoxysilanes in the presence of copper(ii) and sodium or potassium ions. High selectivity of the synthesis of copper/sodium(potassium) organosiloxanes having desired structures can be achieved by choosing the reaction conditions.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. V. A. Igonin, S. V. Lindeman, Yu. T. Struchkov, O. I. Shchegolikhina, A. A. Zhdanov, Yu. A. Molodtsova, and I. V. Razumovskaya, Metalloorg. Khim., 1991, 4, 1355 [Organomet. Chem. USSR, 1991, 4, 672 (Engl. Transl.)].

    Google Scholar 

  2. V. A. Igonin, S. V. Lindeman, Yu. T. Struchkov, Yu. A. Molodtsova, O. I. Shchegolikhina, and A. A. Zhdanov, Izv. Akad. Nauk, Ser. Khim., 1993, 752 [Russ. Chem. Bull., 1993, 42, 718 (Engl. Transl.)].

    Google Scholar 

  3. C. Zucchi, M. Mattioli, G. Gavioli, M. Moret, A. Sironi, R. Ugo, M. Pizzotti, O. I. Shchegolikhina, and G. Pályi, Eur. J. Inorg. Chem., 2000, 1327.

  4. Yu. A. Molodtsova, Yu. A. Pozdnyakova, K. A. Lyssenko, I. V. Blagodatskikh, D. E. Katsoulis, and O. I. Shchegolikhina, J. Organomet. Chem., 1998, 571, 31.

    Google Scholar 

  5. (a) Yu. A. Pozdnyakova, Yu. A. Molodtsova, and O. I. Shchegolikhina, Tez. dokl. III Mezhdunar. simp. po khimii fosfor-, sera-i kremniiorganicheskikh soedinenii "Peterburgskievstrechi" [Abstrs. of Papers, III Intern. Symp. on Chemistry of Organophosphorus,-sulfur, and-silicon Compounds "St.-Petersburg Meeting"] (St. Petersburg, May 31–June 4, 1998), St. Petersburg, 1998, S-155, 306 (in Russian); (b) O. Shchegolikhina, Yu. Pozdniakova, Yu. Molodtsova, I. Blagodatskhih, and D. Katsoulis, Abstr. XII Intern. Symp. on Organosilicon Chemistry (Sendai, Japan, May 23–27, 1999), P180, 234.

  6. (a) M. G. Voronkov and S. V. Basenko, Sov. Sci. Rev. B, 1990, 15, 1; (b) K. A. Andrianov, A. I. Chernyshev, V. A. Temnikovskii, V. V. Yastrebov, and V. M. Kopylov, Teor. Eksp. Khim., 1975, 11, 678 [Theor. Exp. Chem., 1975, 11 (Engl. Transl.)]; (c) K. A. Andrianov, A. I. Chernyshev, V. M. Kopylov, P. L. Prikhod´ko, and S. E. Esipov, Zh. Obshch. Khim., 1980, 50, 1044 [J. Gen. Chem. USSR, 1980, 50 (Engl. Transl.)].

    Google Scholar 

  7. (a) Yu. Pozdniakova, O. Shchegolikhina, B. Herrschaft, N. Auner, and D. Katsoulis, Abstrs. of XII Intern. Symp. on Organosilicon Chemistry (Sendai, Japan, May 23–27, 1999), Sendai, 1999, P180, 234; (b) O. Shchegolikhina, Yu. Pozdniakova, M. Antipin, D. Katsoulis, N. Auner, and B. Herrschaft, Organometallics, 2000, 19, 1077.

    Google Scholar 

  8. O. I. Shchegolikhina, Yu. A. Pozdniakova, Yu. A. Molodtsova, S. D. Korkin, S. S. Bukalov, L. A. Leites, K. A. Lyssenko, A. S. Pergudov, N. Auner, and D. E. Katsoulis, Inorg. Chem., 2002, 41, 6892.

    Google Scholar 

  9. (a) Y. Molodtsova, O. Shchegolikhina, Y. Pozdniakova, I. Blagodatskikh, K. Lyssenko, and D. Katsoulis, Abstr. of IX Intern. Conf. on Inorganic Ring Systems (Saarbruecken, July 23–28, 2000), Saarbruecken, Germany, 2000, P-53; (b) Yu. A. Molodtsova, Yu. A. Pozdnyakova, I. V. Blagodatskikh, K. A. Lyssenko, and O. I. Shchegolikhina, Abstrs. of Mark Vol´pin Memorial Intern. Simp. "Modern Trends in Organometallic and Catalytic Chemistry" (Moscow, 18–23 May, 2003), Moscow, 2003, P-133.

  10. Structural Inorganic Chemistry, Ed. A. F. Wells, Oxford University Press, Oxford, England, 1986.

    Google Scholar 

  11. M. G. Voronkov, V. P. Mileshkevich, and Yu. A. Yuzhelevskii, Siloksanovaya svyaz´ [Siloxane Bond], Nauka, Sibirskoe Otdelenie, Novosibirsk, 1976, 413 pp. (in Russian).

    Google Scholar 

  12. (a) O. Shchegolikhina, L. Matukhina, Yu. Pozdniakova, and D. Katsoulis, Abstrs. of 33d Organosilicon Symposium (Saginaw, Michigan, April 6–8, 2000), Saginaw, Michigan, USA, 2000, A-12; (b) E. V. Matukhina, O. I. Shchegolikhina, N. N. Makarova, Yu. A. Pozdniakova, D. Katsoulis, and Yu. K. Godovskiy, Liq. Cryst., 2001, 28, 869.

  13. (a) O. I. Shchegolikhina, Yu. A. Molodtsova, Yu. A. Pozdnyakova, T. V. Strelkova, and A. A. Zhdanov, Dokl. Akad. Nauk, 1992, 325, 1186 [Dokl. Chem., 1992 (Engl. Transl.)]; (b) O. I. Shchegolikhina, V. A. Igonin, Yu. A. Molodtsova, Yu. A. Pozdnyakova, A. A. Zhdanov, T. V. Strelkova, and S. V. Lindeman, J. Organomet. Chem., 1998, 562, 141.

    Google Scholar 

  14. I. V. Blagodatskikh, O. I. Shchegolikhina, Yu. A. Pozdnyakova, Yu. A. Molodtsova, and A. A. Zhdanov, Izv. Akad. Nauk, Ser. Khim., 1994, 1057 [Russ. Chem. Bull., 1994, 43, 993 (Engl. Transl.)].

    Google Scholar 

  15. (a) Yu. A. Pozdniakova, A. Cornia, G.-L. Abbati, K. A. Lyssenko, and O. I. Shchegolikhina, Abstrs. of Mark Vol´pin Memorial Intern. Symp. "Modern Trends in Organometallic and Catalytic Chemistry" (Moscow, 18–23 May, 2003), Moscow, 2003, P-111; (b) Yu. A. Molodtsova, Yu. A. Pozdnyakova, K. A. Lyssenko, J. W. Bats, N. Auner, and O. I. Shchegolikhina, Abstrs. of Mark Vol´pin Memorial Intern. Symp. "Modern Trends in Organometallic and Catalytic Chemistry" (Moscow, 18–23 May, 2003), Moscow, 2003, P-132.

  16. The Chemist´s Companion, A. J. Gordon and R. A. Ford, A Wiley-Interscience Publication, New York-London-Sydney-Toronto, 1972.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    Yu. A. Molodtsova, Yu. A. Pozdnyakova, I. V. Blagodatskikh, A. S. Peregudov & O. I. Shchegolikhina

Authors
  1. Yu. A. Molodtsova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Yu. A. Pozdnyakova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. I. V. Blagodatskikh
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. S. Peregudov
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. O. I. Shchegolikhina
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Molodtsova, Y.A., Pozdnyakova, Y.A., Blagodatskikh, I.V. et al. Hydrolytic condensation of trialkoxysilanes in the presence of alkali metal and copper(ii) ions. Influence of the reaction conditions on the structure of Cu/M organosiloxanes. Russian Chemical Bulletin 52, 2722–2731 (2003). https://doi.org/10.1023/B:RUCB.0000019892.77263.09

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/B:RUCB.0000019892.77263.09

Search

Navigation