Abstract
Different Zn and Mn-Zn ferrites have been obtained by High Energy Ball Milling (HEBM) from elemental oxides. By varying the rotation speed of vials and main disk, several modes of milling can be obtained. In this paper, the materials prepared by two modes of milling, called shock (S) and high shock (HS), are studied by XRD and Mössbauer spectroscopy. Several mechanisms for spinel phase formation have been proposed. In particular, a reduction of Fe(III) occurs for the S mode, which leads to the formation of a wüstite-type phase which disappears after a long milling time.
Similar content being viewed by others
References
S. D. Shenoy, P. A. Joy and M. R. Anantharaman, J. Magn. Magn. Mater. 269(2004) 217.
N. Guigue-millot, S. Begin-colin, Y. Champion, M. J. Hytch, G. Le caËr and P. Perriat, J. Solid State Chem. 170(2003) 30.
D. J. Fatemi, V. G. Harris, V. M. Browning and J. P. Kirkland, J. Appl. Phys. 83(1998) 6867.
H. Ehrhardt, S. J. Campbell and M. Hofmann, J. Alloys Compd. 339(2002) 255.
M. Abdellaoui and E. Gaffet, ibid. 209(1994) 351.
Idem., Acta Materiala 43(1995) 1087.
J. Teillet, F. Varret and J. Juraszek, unpublished software.
J. Z. Jiang, P. Wynn, S. Morup, T. Okada and F.J. Berry, Nanostruct. Mater. 12(1999) 737.
V. Sepelak, U. Steinike, D. C. Uecker, S. Wi[ss]mann and K. D. Becker, J. Solid State Chem. 135(1998) 52.
D. C. Dobson, J. W. Linnett and M. M. Rahman, J. Phys. Chem. Solids 31(1970) 2727.
C. M. Srivastava, S. N. Shringi and R. G. Srivastava, Phys. Rev. B 14(1976) 2041.
W. A. Kaczmarek and B. W. Ninham, IEEE Trans. Magn. 30(1994) 732.
T. Kosmac and T. H. Courtney, J. Mater. Res. 7(1992) 1519.
V. Sepelak, M. Menzel, K. D. Becker and F. Krumeich, J. Phys. Chem. B 106(2002) 6672.
C. M. Srivastava, S. N. Shringi, R. G. Srivastava and N. G. Nanadikar, Phys. Rev. B 14(1976) 2032.
M. Menzel, V. Sepelak and K. D. Becker, Solid State Ionics 141/142(2001) 663.
V. U. Konig and G. Chol, J. Appl. Cryst. 1(1968) 124.
P. Poix, Sem. Etat Solide 1(1966) 82.
K. KleinstÝck, E. Wieser, P. Kleinert and R. Perthel, Phys. Stat. Sol. 8(1965) 271.
A. H. Morrish and P. E. Clark, Phys. Rev. B 11(1975) 278.
L. Cser, I. DÉzsi, I. Glagkih, L. keszthelyi, D. Kulgawczuk, N. A. Eissa and E. Sterk, Phys. Stat. Sol. 27(1968) 131.
M. El guendouzi, K. Sbai, P. Perriat and B. Gillot, Mater. Chem. Phys. 25(1990) 429.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Verdier, T., Nivoix, V., Jean, M. et al. Characterization of nanocrystalline Mn-Zn ferrites obtained by mechanosynthesis. Journal of Materials Science 39, 5151–5154 (2004). https://doi.org/10.1023/B:JMSC.0000039201.41114.34
Issue Date:
DOI: https://doi.org/10.1023/B:JMSC.0000039201.41114.34