Skip to main content
SpringerLink
Log in

New Preparative Procedure for the Synthesis of Chloroalkyl Sulfides

  • Published:
Russian Journal of Organic Chemistry Aims and scope Submit manuscript

Abstract

Reaction of thiols with dihaloalkanes in the system hydrazine hydrate-base leads to alkyl(chloroalkyl) sulfides with different positions of the chlorine atom with respect to sulfur. The developed one-step procedure for the synthesis of such unsymmetrical sulfides is most suitable for arenethiols and alkanethiols having a long polymethylene chain. The reaction mechanism is discussed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

REFERENCES

  1. Mel'nikov, N.N., Pestitsidy. Khimiya, tekhnologiya i primenenie (Pesticides. Chemistry, Technology, and Application), Moscow: Khimiya, 1987, p. 333.

    Google Scholar 

  2. Comprehensive Organic Chemistry, Barton, D. and Ollis, W.D., Eds., Oxford: Pergamon, 1979, vol. 3. Translated under the title Obshchaya organicheskaya khimiya, Moscow: Khimiya, 1983, vol. 5, p. 226.

    Google Scholar 

  3. Koval', I.V., Usp. Khim., 1993, vol. 63, no. 2, pp. 154-176.

    Google Scholar 

  4. Turchaninova, L.P., Korchevin, N.A., Shipov, A.G., Deryagina, E.N., Baukov, Yu.I., and Voron-kov, M.G., Zh. Obshch. Khim., 1989, vol. 59, no. 3, pp. 722-723.

    Google Scholar 

  5. Pokonova, Yu.V., Galoidsul'fidy (Halogenated Sulfides), Leningrad: Leningr. Gos. Univ., 1977, p. 81.

    Google Scholar 

  6. Poluchenie i svoistva organicheskikh soedinenii sery (Synthesis and Properties of Organic Sulfur Compounds), Belen'kii, L.I., Ed., Moscow: Khimiya, 1998, p. 53.

    Google Scholar 

  7. Kabachnik, M.I. and Godovikov, N.N., Zh. Obshch. Khim., 1963, vol. 63, no. 6, pp. 1941-1945.

    Google Scholar 

  8. Alekminskaya, O.V., Russavskaya, N.V., Korchevin, N.A., and Deryagina, E.N., Russ. J. Gen. Chem., 2002, vol. 72, no. 1, pp. 75-78.

    Google Scholar 

  9. Korchevin, N.A., Podkuiko, P.A., Stankevich, V.K., Deryagina, E.N., and Trofimov, B.A., Russ. J. Gen. Chem., 1995, vol. 65, no. 1, pp. 85-87.

    Google Scholar 

  10. Deryagina, E.N., Korchevin, N.A., Russav-skaya, N.V., and Grabel'nykh, V.A., Izv. Ross. Akad. Nauk, Ser. Khim., 1998, no. 9, pp. 1874-1875.

Download references

Author information

Authors and Affiliations

  1. Favorskii Irkutsk Institute of Chemistry, Siberian Division, Russian Academy of Sciences, ul. Favorskogo 1, Irkutsk, 664033, Russia

    N. V. Russavskaya, N. A. Korchevin, O. V. Alekminskaya, E. N. Sukhomazova, E. P. Levanova & E. N. Deryagina

Authors
  1. N. V. Russavskaya
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. N. A. Korchevin
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. O. V. Alekminskaya
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. E. N. Sukhomazova
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. E. P. Levanova
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. E. N. Deryagina
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Russavskaya, N.V., Korchevin, N.A., Alekminskaya, O.V. et al. New Preparative Procedure for the Synthesis of Chloroalkyl Sulfides. Russian Journal of Organic Chemistry 38, 1445–1448 (2002). https://doi.org/10.1023/A:1022540002086

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1022540002086

Keywords

Search

Navigation