Abstract
The adsorption of cobalt(II) was studied on silica gel with chemically bound triphenylphosphonium groups. Cobalt was quantitatively recovered only in the presence of an additional ligand, nitroso-R-salt, in the solution. A sorption–spectrometric procedure was developed for determining cobalt in waters and alloys.
Similar content being viewed by others
REFERENCES
Ivanov, V.M., Morozko, S.A., and Zolotov, Yu.A., Zh. Anal. Khim., 1993, vol. 48, no. 8, p. 1389.
Ivanov, V.M. and Kuznetsova, O.V., Zh. Anal. Khim., 1995, vol. 50, no. 5, p. 498.
Maksimova, I.M. and Morosanova, E.I., Zh. Anal. Khim., 1994, vol. 49, no. 6, p. 602.
Amelin, V.G., Zh. Anal. Khim., vol. 55, no. 9, p. 902.
Modifitsirovannye kremnezemy v sorbtsii, katalize i khromatografii (Modified Silicon Dioxides in Sorption, Catalysis, and Chromatography), Lisichkin, G.V., Ed.,Moscow: Khimiya, 1986.
Tikhomirova, T.M., Luk'yanova, M.V., Fadeeva, V.M., et al., Zh. Anal. Khim., 1993, vol. 48, no. 1, p. 73.
Runov, V.K., Strepetova, T.V., Pukhovskaya, V.M., et al., Zh. Anal. Khim., 1993, vol. 48, no. 11, p. 43.
Pyatnitskii, I.V.,Analiticheskaya khimiya elementov:kobal't (Analytical Chemistry of Elements: Cobalt), Moscow: Nauka, 1965.
Ivanov, V.M., Geterotsiklicheskie azotsoderzhashchie azosoedineniya (Heterocyclic Nitrogen-Containing Azo Compounds), Moscow: Nauka, 1982.
Vovk, M.V., Trofimchuk, A.K., Tryashin, A.S., and Samarai, L.I., USSR Inventor's Certificate no. 1839170, Byull. Izobret., no. 48, 1993.
Turker, A. and Tunceli, A., Fresenius' J. Anal. Chem., 1993, vol. 345, no. 12, p. 755.
D'yachenko, N.A., Trofimchuk, A.K., and Sukhan, V.V., Zh. Anal. Khim., 1999, vol. 54, no. 2, p. 159.
Nakashima, T., Yoshimura, K., and Waki, H., Talanta, 1990, vol. 37, no. 7, p. 735
GOST (State Standard) 6689.9-80: Nickel and Copper-Nickel Alloys. Procedure for Cobalt Determination, 1980.
GOST (State Standard) 6689.9-92: Nickel, Nickel and Copper-Nickel Alloys. Procedure for Cobalt Determination,1992.
Lur'e, Yu.Yu., Analiticheskaya khimiya promyshlennykh stochnykh vod (Analytical Chemistry of Industrial Sewage Waters), Moscow: Khimiya, 1984.
Tabenskaya, T.V., Zaporozhets, O.A., Boryak, A.K., et al., Ukr. Khim. Zh., 2000, vol. 66, no. 1, p. 41.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
D'yachenko, N.A., Trofimchuk, A.K. & Sukhan, V.V. Sorption of Cobalt as a Nitroso-R-Salt Complex on Silica Gels Modified with Triphenylphosphonium Groups Followed by Determination in the Adsorbent Phase. Journal of Analytical Chemistry 57, 1022–1024 (2002). https://doi.org/10.1023/A:1020977407784
Issue Date:
DOI: https://doi.org/10.1023/A:1020977407784