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Tricyclo[7.3.1.02,7]tridecanes with an Amino Group at the Bridging Carbon. Synthesis and Stereochemistry

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Abstract

Hydroamination of tricyclo[7.3.1.02,7]tridec-2(7)-en-13-one according to Leukart reaction furnished (tricyclo[7.3.1.02,7]tridec-2(7)-en-13-yl)methanamides stereoisomeric at C13 atom. The corresponding epoxides were prepared therefrom. The unsaturated and epoxidized methanamides were hydrolyzed into amines that were converted into Schiff bases.The configurations of substances were established.

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Authors and Affiliations

  1. Far-Eastern State University, Vladivostok, 690600, Russia

    V. I. Vysotskii, O. V. Patrusheva & T. A. Vysotskaya

  2. Far-Eastern Division, Pacific Institute of Biological Chemistry, Russian

    V. V. Isakov

Authors
  1. V. I. Vysotskii
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  2. O. V. Patrusheva
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  3. T. A. Vysotskaya
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  4. V. V. Isakov
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Vysotskii, V.I., Patrusheva, O.V., Vysotskaya, T.A. et al. Tricyclo[7.3.1.02,7]tridecanes with an Amino Group at the Bridging Carbon. Synthesis and Stereochemistry. Russian Journal of Organic Chemistry 38, 1130–1136 (2002). https://doi.org/10.1023/A:1020941207804

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  • DOI: https://doi.org/10.1023/A:1020941207804

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