Abstract
The kinetic features of magnesium oxidation with benzoyl chloride in a mixture of tetrahydrofuran and benzene were studied. A reaction mechanism was suggested, involving attack of the oxidant molecule adsorbed on the metal surface by a similar molecule from the bulk of the solution.
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REFERENCES
Coppinger, A.M., J. Am. Chem. Soc., 1954, vol. 76, no. 7, pp. 1372-1381.
Pearl, I.A., Evans, T.N., and Dehn, W.M., J. Am. Chem. Soc., 1938, vol. 60, no. 15, pp. 2978-2980.
Varvoglos, G.A., Ber., 1937, vol. 70, pp. 2391-2396.
Lapkin, I.I. and Povarnitsyna, T.N., Zh. Obshch. Khim., 1968, vol. 38, no. 1, pp. 99-102.
Lapkin, I.I., Anvarova, G.Ya., and Povarnitsyna, T.N., Zh. Obshch. Khim., 1966, vol. 36, no. 11, pp. 1952-1953.
Sergeeva, V.P., Maslennikov, V.P., Spirina, I.V., and Maslennikov, S.V., Vestn. Nizhegor. Gos. Univ., Ser. Khim., 1998, no. 1, pp. 153-164.
Maslennikov, S.V. and Spirina, I.V., Zh. Obshch. Khim., 1998, vol. 68, no. 2, pp. 300-302.
Entelis, S.T. and Tiger, R.P., Kinetika reaktsii v zhidkoi faze. Kolichestvennyi uchet vliyaniya sredy (Kinetics of Liquid-Phase Reactions. Quantitative Consideration of Solvent Effects), Moscow: Khimiya, 1975, p. 209.
Gray, A.R. and Fuson, R.C., J. Am. Chem. Soc., 1934, vol. 56, no. 3, pp. 739-741.
Rybakova, L.F., Syutkina, O.P., Stepanova, T.A., and Petrov, E.S., Zh. Obshch. Khim., 1995, vol. 65, no. 1, pp. 1600-1603.
Novotorova, M.N., Syutkina, O.P., Rybakova, L.F., and Petrov, E.S., Zh. Obshch. Khim., 1998, vol. 68, no. 1, pp. 73-75.
Bellamy, L.J., The Infra-Red Spectra of Complex Molecules, New York: Wiley, 1957.
Palston, A.W. and Selby, W.M., J. Am. Chem. Soc., 1939, vol. 61, no. 5, pp. 1019-1020.
Gordon, A.J. and Ford, R.A., The Chemist's Companion. A Handbook of Practical Data, Techniques, and References, New York: Wiley, 1972.
Zakharov, V.A., Makhtarulin, S.I., and Ermakov, Yu.I., USSR Inventor's Certificate no. 726 702, 1980, Byull. Izobret., 1981, no. 13, p. 266.
Charlot, G., Les methods de la chimie analytique. Analyse quantitative minerale, Paris: Masson, 1961, 4th ed. Translated under the title Metody analiticheskoi khimii. Kolichestvennyi analiz neorganicheskikh soedinenii, Moscow: Khimiya, 1965, p. 678.
Organic Syntheses, Blatt, A.H., Ed., New York: Wiley, 1944. Translated under the title Sintezy organicheskikh preparatov, Moscow: Inostrannaya Literatura, 1953, coll. vol. 4, p. 528.
Chirkov, N.M., Entelis, S.G., and Kondrat'eva, G.P., Vysokomol. Soedin., 1961, vol. 3, no. 6, pp. 1044-1053.
Zhukov, S.A., Lavrentyev, I.P., and Nifontova, T.A., Kinet. Catal. Lett., 1977, vol. 7, no. 4, pp. 405-412.
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Maslennikov, S.V., Sergeeva, V.P., Spirina, I.V. et al. Oxidation of Magnesium with Benzoyl Chloride in a Mixture of Tetrahydrofuran and Benzene. Russian Journal of General Chemistry 72, 678–680 (2002). https://doi.org/10.1023/A:1019583513232
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DOI: https://doi.org/10.1023/A:1019583513232