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Generation of superoxide ions at oxide surfaces

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Abstract

The superoxide radical anion O2 - is both an important intermediate in heterogeneous catalytic oxidation and a useful probe for positive charges in ionic solids, such as metal oxides and zeolites. The paper illustrates the main circumstances under which stable superoxide anions are formed at surfaces: (i) direct surface–oxygen electron transfer; (ii) photoinduced electron transfer; (iii) surface intermolecular electron transfer; (iv) decomposition of hydrogen peroxide.

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Authors and Affiliations

  1. Department of Applied Chemistry, College of Engineering, Osaka Prefecture University, Gakuen-cho 1-1, Sakai, Osaka, 599-8531, Japan

    Masakazu Anpo

  2. Laboratoire de Réactivité de Surfaces, Université P. et M. Curie (Paris VI), 4 Place Jussieu, 75252, Paris, France

    Michel Che

  3. Dipartimento di Chimica IFM, Università di Torino, Via P. Giuria 9, 10125, Torino, Italy

    Bice Fubini, Edoardo Garrone, Elio Giamello & Maria Cristina Paganini

Authors
  1. Masakazu Anpo
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  2. Michel Che
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  3. Bice Fubini
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  4. Edoardo Garrone
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  5. Elio Giamello
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  6. Maria Cristina Paganini
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Anpo, M., Che, M., Fubini, B. et al. Generation of superoxide ions at oxide surfaces. Topics in Catalysis 8, 189–198 (1999). https://doi.org/10.1023/A:1019117328935

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