Abstract
The laser Raman spectra of MoO3 and NiO–MoO3 supported on gallia and gallium–aluminum mixed oxides are presented and correlated to the type of support and the hydrodesulfurization (HDS) activity of the catalysts. The results show that the support affects the species (orientation of catalyst) that are formed on its surface. For example, MoO3 forms mainly HDS inactive tetrahedral species on gallia; on alumina surface, it forms the HDS active polymeric octahedral species. Also, bulk oxide is formed more readily on gallia than on alumina. On addition of NiO, as a promoter, to the MoO3 catalyst supported on gallia, a band that can be assigned to HDS inactive species was also formed. The intensity of this band is low in the spectra of NiO–MoO3 catalysts supported on alumina.
Similar content being viewed by others
References
T.C. Ho, J. Catal. 131 (1991) 298.
N. Satterfield, Heterogeneous Catalysis in Industrial Practice (McGraw-Hill, New York, 1991) p. 373.
R. Le Van Mao, R. Carli, J. Yao and V. Tagani, Catal. Lett. 16 (1992) 43.
S.K. Saha and S. Sivasanker, Catal. Lett. 15 (1992) 413.
G. Buckles, G.J. Hutchings and C.D. Williams, Catal. Lett. 11 (1991) 89.
T. Olorunyolemi and R.A. Kydd, J. Catal. 158 (1996) 583.
S.S. Chan and I.E. Wachs, J. Catal. 103 (1987) 224.
M.A. Vuurman and I.E. Wachs, J. Phys. Chem. 96 (1992) 5008.
M.A. Vuurman, I.E. Wachs, D.J. Stufkensand and A. Oskam, in: Spectroscopic Characterization of Supported Metal Oxide Catalysts, ed. M.A. Vuurman (1992) p. 137.
F.R. Brown, L.E. Makovsky and K.E. Rhee, J. Catal. 50 (1977) 385.
A. Jannibello and P.C.H. Mitchell, in: 2nd Int. Symp. Scientific Basis for the Preparation of Heterogeneous Catalysts, Louvain-la-Neuve, Belgium, 1978, p. E2.
H. Knözinger and H. Jeziorowski, J. Phys. Chem. 82 (1978) 2002.
A. Jannibello, S. Marengo, F. Trifirò and P.L. Villa, in: 2nd Int. Symp. Scientific Basis for the Preparation of Heterogeneous Catalysts, Louvain-la-Neuve, Belgium, 1978, p. A5.
C.P. Cheng and G.L. Scrader, J. Catal. 60 (1979) 276.
H. Jeziorowski and H. Knözinger, J. Phys. Chem. 83 (1979) 1166.
N. Giordano, J.C.J. Bart, A. Vaghi, A. Castellan and G. Martinotti, J. Catal. 36 (1975) 81.
L. Wang and W.K. Hall, J. Catal. 82 (1983) 177.
G.L. Scrader and C.P. Cheng, J. Catal. 80 (1983) 369.
J.M. Stencel, L.E. Makovsky, J.R. Diehl and T.A. Sarkus, J. Catal. 95 (1985) 4141.
E. Payen, S. Kasztelan, J. Grimblot and J.P. Bonnell, J. Mol. Struct. 143 (1986) 259.
E. Payen, S. Kasztelan, J. Grimblot and J.P. Bonnell, J. Raman Spectrosc. 17 (1986) 233.
F.D. Hardcastle and I.E. Wachs, J. Raman Spectrosc. 21 (1990) 683.
M. de Boer, A.J. van Dillen, D.C. Koningsberger, J. Geus, M.A. Vuurman and I.E. Wachs, Appl. Catal. 11 (1991) 227.
H. Hu, I.E. Wachs and S.R. Bare, J. Phys. Chem. 99 (1995) 10897.
G. Mestl and T.K.K. Srinivasan, Catal. Rev. Sci. Eng. 40 (1998) 451.
T. Olorunyolemi, Ph.D. dissertation, University of Calgary (1995).
T. Olorunyolemi and R.A. Kydd, Catal. Lett. 59 (1999) 27.
A.J.A. Konings, A.M. van Dooren, D.C. Koningsberger, V.H.J. de Beer, A.L. Farragher and G.C.A. Schuit, J. Catal. 54 (1978) 1.
A.J.A. Konings, W.L.J. Brentjens, D.C. Koningsberger and V.H.J. de Beer, J. Catal. 67 (1981) 145.
A.J.A. Konings, A. Valster, V.H.J. de Beer and R. Prins, J. Catal. 76 (1982) 466.
N.-Y. Topsøe and H.J. Topsøe, J. Catal. 84 (1983) 386.
R. Mattes, H. Bierbüsse and J. Fuchs, Z. Anorg. Allg. Chem. 385 (1971) 230.
D.S. Zingg, L.E. Makovsky, R.E. Tischer, F.R. Brown and D.M. Hercules, J. Phys. Chem. 84 (1980) 2898.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Olorunyolemi, T., Kydd, R.A. Laser Raman spectroscopy of MoO3 and NiO–MoO3 supported on gallia and gallium–aluminum mixed oxides. Catalysis Letters 65, 185–192 (2000). https://doi.org/10.1023/A:1019046127985
Issue Date:
DOI: https://doi.org/10.1023/A:1019046127985