Abstract
The deformation behaviour and the fracture resistance of a range of nylon 6,6/ABS alloys of varying composition both with and without the presence of glass fibres were investigated. The deformation behaviour was characterized by careful measurements of the volumetric strain during tensile tests in order to understand the relative roles of cavitation and shear yielding in these materials. The fracture resistance was investigated in detail in the fracture mechanics sense by characterizing the J-integral fracture initiation toughness. In materials exhibiting stable crack growth, a new parameter, namely, the plateau value of the J-integral fracture resistance curve, was measured directly and represented the resistance of the material to stable crack growth. The results showed that the relationship between the deformation behaviour and fracture resistance was related to the extent of damage that developed in the crack-tip zone. Substantial additional toughening was developed during the crack extension stage both in the presence and absence of glass fibres. Glass fibres were found to promote shear yielding and, as a result, enhance both the fracture initiation as well as the fracture propagation resistance of the nylon 6,6/ABS alloys.
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H. BREUER, F. HAAF and J. STABENOW, J. Macromol. Sci. Phys. B1 (1977) 387.
A. M. DONALD and E. J. KRAMER, J. Mater. Sci. 17 (1982) 1765.
A. M. DONALD and E. J. KRAMER, J. Mater. Sci. 17 (1982) 2351.
M. E. FOWLER, H. KESKULA and D. R. PAUL, J. Appl. Polym. Sci. 35 (1988) 1563.
C. B. BUCKNALL, P. S. HEATHER and A. LAZZER, J. Mater. Sci. 16 (1989) 2255.
R. A. BUBECK, D. J. BUCKLEY, Jr, E. J. KRAMER and H. R. BROWN, ibid. 26 (1991) 6249.
B. MAJUMDAR, H. KESKULA and D. B. PAUL, J. Polym. Sci. B Polym. Phys. 32 (1994) 2127.
H.-J. SUE and A. F. YEE, in “ANTEC Conference Proceedings”, Vol. 2 (1995) pp. 1517–18.
S. V. NAIR, A. SUBRAMANIAM and L. A. GOETTLER, J. Mater. Sci. 32 (1997) 5321.
S. V. NAIR, A. SUBRAMANIAM and L. A. GOETTLER, J. Mater. Sci., submitted.
S. V. NAIR and A. SUBRAMANIAM, J. Mater. Sci., submitted.
L. A. VESTERGAARD, S. V. NAIR and L. A. GOETTLER, J. Mater. Sci., submitted.
L. A. VESTERGAARD, S. V. NAIR and L. A. GOETTLER, J. Mater. Sci., submitted.
US Pat. 4713 415 (1987).
US Pat. 5227 428 (1993).
R. E. LAVENGOOD and F. M. SILVER, in “ANTEC Conference Proceedings” (1987) p. 1369.
R. E. LAVENGOOD and F. M. SILVER, in “SPE RETEC Conference Proceedings” (1987) p. 299.
D. M. OTTERSON, B. H. KIM and R. E. LAVENGOOD, J. Mater. Sci. 26 (1991) 1478.
B. MAJUMDAR, H. KESKULA and D. R. PAUL, Polymer 35 (1994) 5453.
B. MAJUMDAR, H. KESKULA and D. R. PAUL, Polymer. 35 (1994) 5468.
B. MAJUMDAR, H. KESKULA, D. R. PAUL and N. G. HARVEY, ibid. 35 (1994) 4263.
B. MAJUMDAR, H. KESKULA and D. R. PAUL, ibid. 35 (1994) 3164.
S. V. NAIR, S.-C. WONG, A. SUBRAMANIAM, L.A. GOETTLER and L. A. GUSTAFSON, in “ANTEC Conference Proceedings” (1995) p. 41.
B. H. KIM and C. R. JOE, Engng Frac. Mech. 34 (1989) 221.
T. HASHIDA and V. C. LI, J. Amer. Ceram. Soc. 77 (1994) 1553.
S. V. NAIR and Y-L. WANG, J. Amer. Ceram. Soc. (1995) in press.
D. S. PARKER, H.-J. SUE, J. HUANG and A. F. YEE, Polymer 31 (1990) 2267.
M. L. SHIAO, S. V. NAIR, P. D. GARRETT and R. E. POLLARD, ibid. 35 (1994) 306.
C. B. BUCKNALL, P. HEATHER and A. LAZZERI, J. Mater. Sci. 24 (1989) 1489.
S. V. NAIR, M. L. SHIAO and P. D. GARRETT, ibid. 22 (1992) 1085.
M. L. SHIAO, S. V. NAIR, P. D. GARRETT and R. E. POLLARD, ibid. 29 (1994) 1739.
S. V. NAIR and S.-C. WONG, ein “ASME Conference Proceedings”, Chicago, November 1994 (ASME, New York, 1995).
A. G. EVANS, F. ZOK and T. J. MACKIN, in “High Temperature Mechanical Behavior of Ceramic Matrix Composites”, edited by S. V. Nair and K. Jakus (Butterworth-Hienneman, Boston, 1995) pp. 3–84.
S. KUNZ-DOUGLASS, P W. R. BEAUMONT and M. F. ASHBY, J. Mater. Sci. 15 (1990) 1109.
A. G. EVANS, Z. B. AHMAD, D. G. GILBERT and P. W. R. BEAUMONT, Acta Metall. 34 (1986) 1.
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Nair, S.V., Wong, SC. & Goettler, L.A. Fracture resistance of polyblends and polyblend matrix composites: Part I Unreinforced and fibre-reinforced nylon 6,6/ABS polyblends. Journal of Materials Science 32, 5335–5346 (1997). https://doi.org/10.1023/A:1018618912039
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DOI: https://doi.org/10.1023/A:1018618912039