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Antimony(III) Complexes with Quaternary Ammonium Bases: Synthesis, Spectral, and Luminescent Properties

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Abstract

Complexes of antimony(III) halides with quaternary ammonium bases of different composition were synthesized and characterized by elemental and X-ray diffraction analyses and IR and luminescence spectroscopy. For complexes [R"3R"N]SbHal4 (Hal = Cl–, Br–, R" = R" = CH3, C2H5, C4H9), the maximum of the emission band and fluorescence intensity was found to depend on the nature of the halide ion and the alkyl radical length.

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  1. Far East Division, Russian Academy of Sciences, Institute of Chemistry, pr. Stoletiya Vladivostoka 159, Vladivostok, 690022, Russia

    N. V. Petrochenkova, T. V. Storozhuk, A. G. Mirochnik & V. E. Karasev

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  1. N. V. Petrochenkova
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  2. T. V. Storozhuk
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  3. A. G. Mirochnik
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  4. V. E. Karasev
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Petrochenkova, N.V., Storozhuk, T.V., Mirochnik, A.G. et al. Antimony(III) Complexes with Quaternary Ammonium Bases: Synthesis, Spectral, and Luminescent Properties. Russian Journal of Coordination Chemistry 28, 468–472 (2002). https://doi.org/10.1023/A:1016245126807

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