Skip to main content
Log in

Kinetics of Formation and Curing of Oligoether Urethane Allyl Ester

  • Published:
Russian Journal of Applied Chemistry Aims and scope Submit manuscript

Abstract

Kinetic parameters of formation of P-9AD oligoether urethane allyl ester with terminal double bonds and of its curing with dinitrile oxide were determined. The dependence of the rate constant on the allyl alcohol concentration and temperature was studied. The mechanism of reaction of P-9A prepolymer with allyl alcohol was proposed. The kinetic and thermodynamic parameters of curing of oligoether urethane allyl ester with dinitrile oxide were determined. The mechanism of reaction of P-9AD oligoether urethane allyl ester with dinitrile oxide was proposed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

REFERENCES

  1. Antipova, V.F., Petrov, G.N., and Salins, K.Yu., Primenenie nitriloksidov v kachestve otverditelei kauchukov obshchego naznacheniya (The Use of Nitrile Oxides as Curing Agents for Rubbers of General Purpose), Zhukov, B.P., Ed., Ser.: Porokha i tverdye spetsial'nye topliva v narodnom khozyaistve (Gunpowder and Solid Special Fuels in National Economy), Moscow: TsNIINTKPK, 1990.

    Google Scholar 

  2. Berlin, A.A., Korolev, G.V., and Kefeli, T.Ya., Akrilovye oligomery i materialy na ikh osnove (Acrylic Oligomers and Materials Based on Them), Moscow: Khimiya, 1983.

    Google Scholar 

  3. Saunders, J.H. and Frish, K.C., Polyurethanes. Chemistry and Technology, part 1: Chemistry, New York: Interscience, 1962.

    Google Scholar 

  4. Carey, F.A. and Sundberg, R.J., Advanced Organic Chemistry, part A: Structure and Mechanisms, New York: Plenum, 1977.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kotel'nikov, S.A., Sukhinin, V.S. & Ermilov, A.S. Kinetics of Formation and Curing of Oligoether Urethane Allyl Ester. Russian Journal of Applied Chemistry 75, 477–479 (2002). https://doi.org/10.1023/A:1016171511244

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1016171511244

Keywords

Navigation