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Ruthenium-Catalyzed Aerobic Oxidation of Alcohols on Zeolite-Encapsulated Cobalt Salophen Catalyst

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Abstract

A zeolite-encapsulated cobalt salophen catalyst was prepared by the intrazeolite ligand synthesis method. This catalyst proved to be active in the ruthenium-catalyzed oxidation of primary and secondary alcohols to aldehydes or ketones. Several advantages of the heterogenized catalyst was found in this system compared to the homogeneous counterpart, namely easy handling and better performance (less sensitive to solvent effects, higher specific rates).

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Zsigmond, Á., Notheisz, F., Csjernyik, G. et al. Ruthenium-Catalyzed Aerobic Oxidation of Alcohols on Zeolite-Encapsulated Cobalt Salophen Catalyst. Topics in Catalysis 19, 119–124 (2002). https://doi.org/10.1023/A:1013893502340

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