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Chemical Characterization of Acid Fog and Rain in Northern Japan Using Back Trajectory and Oblique Rotational Factor Analysis

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Abstract

Fog/cloud and rain water were collected at the mountainside of Hachimantai range in northern Japan and rain water was also collected at Akita City in order to investigate the air pollutant scavenging mechanism. The concentrations of various ions in these samples were analyzed, and the fog drop size and the wind direction were measured at each fog event. The fog at Hachimantai range had a very high total ion concentration, and was considerably acidified by non sea salt (nss-) SO4 2− and NO3 , compared with the rain at Akita and all sites in Hachimantai range. Using the oblique rotational factor analysis, three factors were extracted as the air pollutants; A: (NH4)2SO4+H2SO4, B: sea salts+HNO3+H2SO4, C: NH4NO3+OH. These salts are well-known as the cloud condensation nuclei (CCN). Combining the factor analysis with the 72h back trajectory at 850hPa level, the contribution of Factor A was closely connected to the long-range transportation of anthropogenic or natural aerosol in air masses of continental origin.

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References

  • Hoag, K.J., Collet, Jr., J.L. and Pandis, S.N.: 1999, The influence of Drop Size-dependent fog Chemistry on Aerosol Processing by San Joaquin Valley Fogs, Atmospheric Environment 33, 4817–4832.

    Google Scholar 

  • Hosono, T., Okochi, H., Igawa, M.: 1994, Fog water chemistry at a mountainside in Japan, Bulletin of Chemical Society of Japan 67, 368–374.

    Google Scholar 

  • Ogawa, N., Adzuhata, T., and Kajikawa, M.: 1998a, Chemical characterization of acid snowfall in the coast and inland areas of Akita Prefecture in Japan, Seppyo 60, 143–156.

    Google Scholar 

  • Ogawa, N., Kikuchi, R., Goto, H., Kajikawa, M., Ozeki, T., 1998b: Evaluation of sea-salt origin pollutants in precipitation at Akita using constrained oblique rotational factor analysis, Bunseki Kagaku 47(8), 503–511 (in Japanese).

    Google Scholar 

  • Ogawa, N., Kikuchi, R., Okamura, T., Adzuhata, T., Kajikawa, M., and Ozeki, T.: 1999a, Cloud droplet size dependence of the concentrations of various ions in cloud water at a mountain ridge in northern Japan, Atmospheric Research 51, 77–80.

    Google Scholar 

  • Ogawa, N., Kikuchi, R., Okamura, T., Kajikawa, M., Adzuhata, T., Iwata, Y., and Ozeki, T.: 1999b, Chemical Characterization of Acid Precipitation and Fog of Akita Prefecture in Japan, International Journal of The Materials Engineering for Resources 7, 282–295.

    Google Scholar 

  • Ogawa, N., Kikuchi, R., Okamura, T., Inotsume, J., Adzuhata, T., Ozeki, T., and Kajikawa, M.: 2000, Evaluation of ionic pollutants in cloud droplets at a mountain ridge in northern Japan using constrained oblique rotational factor analysis, Atmospheric Research, 54, 277–283.

    Google Scholar 

  • Okita, T.: 1961, Size distribution of large droplets in precipitating clouds, Tellus 13, 509–521.

    Google Scholar 

  • Ozeki, T., Koike, K., and Kimoto, T.: 1995, Evaluation of Sources of Acidity in Rainwater using a Constrained Oblique Rotational Factor Analysis, Environmental Science and Technology 29, 1638–1645.

    Google Scholar 

  • Ozeki, T., Koike, K., Ogawa, N., Adzuhata, T., Kajikawa, M., and Kimoto, T.: 1997, Numerical Evaluation of Features of Polutant Sources Extracted by Constrained Oblique Rotational Factor Analysis for Precipitation Data. Extraction of Features of Precipitations at Hyogo and Akita Areas, Analytical Sciences 13, 169–176.

    Google Scholar 

  • Pruppacher, H.R., and Klett, J.D.: 1997, ‘Microphysics of Clouds and Precipitation', Kluwer Academic Publishers, Chap. 17, pp. 700–791.

  • Seinfeld, J.M., Pandis, S.N.: 1998, ‘Atmospheric Chemistry and Physics', Wiley, New York.

    Google Scholar 

  • Waldman, J.M., Munger, J.W., Jacob, D.J., Flagan, R.C., Morgan, J.J., Hoffman, M.R.: 1982, Chemical composition of acid fog, Science 218, 677–680.

    Google Scholar 

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Adzuhata, T., Okamura, T., Inotsume, J. et al. Chemical Characterization of Acid Fog and Rain in Northern Japan Using Back Trajectory and Oblique Rotational Factor Analysis. Water, Air, & Soil Pollution 130, 337–342 (2001). https://doi.org/10.1023/A:1013812613373

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