Skip to main content
Log in

Structure of Free Radicals Formed under X-ray Irradiation of Organic Polymeric Acids

  • Published:
Russian Journal of Applied Chemistry Aims and scope Submit manuscript

Abstract

The structure of free radicals formed under X-ray irradiation of polyacrylic and polymetharcylic acids and poly-3-vinyltetrazole was studied by ESR spectroscopy. In polymerization of polymethacrylic acid, the conditions of the polymer recovery from the solution affect the nature of the radiolysis products.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

REFERENCES

  1. Roth, H.-K., Keller, F., and Schneider, H., Hochfrequenzspektroskopie in der Polymerforschung, Berlin: Akademie, 1984.

    Google Scholar 

  2. Atkins, P.W. and Symon, M.C.R., The Structure of Inorganic Radicals. An Application of Electron Spin Resonance to the Study of Molecular Structure, Amsterdam: Elsevier, 1967.

    Google Scholar 

  3. Ingram, D.J.E., Symons, M.C.R., and Townsend, M.G., Trans. Faraday Soc., 1958, vol. 54, no. 3, pp. 409-413.

    Google Scholar 

  4. Ormerod, M.G. and Charlesby, A., Polymer, 1965, vol. 5, no. 1, pp. 67-72.

    Google Scholar 

  5. Clay, M.R. and Charlesby, A., Eur. Polym. J., 1975, vol. 11, no. 1, pp. 187-193.

    Google Scholar 

  6. Shioji, S., Ohinishi, S., and Nitta, I., J. Polym. Sci., Ser. A-1, 1963, vol. 3, no. 2, pp. 373-381.

    Google Scholar 

  7. Sanjeeva Rao, B. and Ramakrishna Murthy, M., J. Polym. Sci., Polym. Phys. Ed., 1989, vol. 27, no. 5, pp. 1187-1194.

    Google Scholar 

  8. Bresler, S.E., Kazbekov, E.N., and Saminskii, E.M., Vysokomol. Soedin., 1959, vol. 1, no. 9, pp. 1374-1382.

    Google Scholar 

  9. Tomashevskii, E.N. and Kvachadze, N.G., Vysokomol. Soedin., Ser. B, 1995, vol. 37, no. 10, pp. 1788-1792.

    Google Scholar 

  10. Tatar, L. and Kaptan, Y., J. Polym. Sci., Polym. Phys. Ed., 1997, vol. 35, no. 9, pp. 2195-2200.

    Google Scholar 

  11. Iwasaki, M. and Sakai, Y., J. Polym. Sci., Ser. A-1, 1969, vol. 7, no. 6, pp. 1532-1544.

    Google Scholar 

  12. Carrington, A. and McLachlan, A.D., Introduction to Magnetic Resonsnce with Applications to Chemistry and Chemical Physics, London: Chapman, 1979.

    Google Scholar 

  13. Saraev, V.V., Kraikivskii, P.B., Lazarov, P.G., et al., Koord. Khim., 1996, vol. 22, no. 9, pp. 648-654.

    Google Scholar 

  14. Voevodskii, V.V., Fizika i khimiya elementarnykh khimicheskikh protsessov (Physics and Chemistry of Elementary Chemical Processes), Moscow: Nauka, 1969.

    Google Scholar 

  15. Saraev, V.V., Alsarsur, I.A., Annenkov, V.V., and Shchipunov, D.V., Koord. Khim., 1999, vol. 25, no. 12, pp. 919-922.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Saraev, V.V., Alsarsur, I.A., Annenkov, V.V. et al. Structure of Free Radicals Formed under X-ray Irradiation of Organic Polymeric Acids. Russian Journal of Applied Chemistry 74, 1585–1589 (2001). https://doi.org/10.1023/A:1013790126220

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1013790126220

Keywords

Navigation