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The Adsorption of Fluoride Ion from Aqueous Solution by Activated Alumina

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Abstract

The adsorption of fluoride ion in aqueous solution by using alumina was studied in this research. The experimental resultsindicated that the removal efficiency was influenced significantly by solution pH and the optimum operating pH wasfound to be in the range of 5 to 7. For neutral and acidic solutions, the adsorption capacities of fluoride by alumina wasinterfered by the presence of sulfate. The Langmuir and Freundlich isotherms can well describe the equilibrium behaviorsof the adsorption processes. The experimentally determined lowvalues of activation energy indicate nonspecific adsorption isthe predominant mechanism. The surface reaction-limiting batchkinetic model can adequately describe the removal behaviors offluoride ion by alumina adsorption in the batch system.

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References

  • Bishop, P. L. and Sansoucy, G.: 1978, ‘Fluoride Removal from Drinking Water by Fluidized Activated Alumina Adsorption’, J. Am. Water Asso. 70, 554–559.

    Google Scholar 

  • Chaturvedi, A. K., Yadava, K. P., Pathak, K. C. and Singh, V. N.: 1990, ‘Defluoridation of Water by Adsorption on Fly Ash’, Wat. Air Soil Pollut. 49(12), 51–61.

    Google Scholar 

  • Chikuma, M. and Nishimura, M.: 1990, ‘Selective Sorption of Fluoride Ion by Anion-exchange Resin Modified with Alizarin Fluorine Blue-praseodymium (III) Complex’, Reactive Polymer, 13(1-2), 131–138.

    Google Scholar 

  • Choi, W. W. and Chen, K. Y.: 1979, ‘The Removal of Fluoride from Waters by Adsorption’, J. Am. Water Works Assoc. 71, 562–570.

    Google Scholar 

  • Faust, S. D. and Aly, O. M.: 1987, Adsorption Processes for Water Treatment, Butterworth, Boston, MA, U.S.A.

    Google Scholar 

  • Fogler, H. S.: 1999, Elements of Chemical Reaction Engineering, 3rd (ed.), Prentice-Hall, Upper Saddle River, NJ, U.S.A.

    Google Scholar 

  • Hao, O. J. and Huang, C. P.: 1986, ‘Adsorption Characteristics of Fluoride onto Hydrous Alumina’, J. Envron. Engr. (ASCE) 112(6), 1054–1069.

    Google Scholar 

  • Haron, M. J., Wan Yunus, W. M. Z., Wasay, S. A., Uchiumi, A. and Tokunaga, S.: 1995, ‘Sorption of Fluoride Ions from Aqueous Solutions by a Yttrium-loaded Poly(Hydroxamic Acid) Resin’, Int. J. Environ. Studies 48, 245–255.

    Google Scholar 

  • Kanesato, M., Yokoyama, T. and Suzuki, T. M.: 1988, ‘Selective Adsorption of Fluoride Into by La(III)-loaded Chelating Resin Having Phosphonmethylamino Groups’, Chem. Letters 2, 207–210.

    Google Scholar 

  • Morel, F. M. M. and Hering, J. G.: 1993, Principles and Applications of Aqueous Chemistry, John Wiley and Sons, Inc., NY, U.S.A.

    Google Scholar 

  • Park, S. W. and Huang, C. P.: 1987, ‘The Surface Acidity of Hydrous CdS(S)’, J. Colloid Interf. Sci. 117(2), 431–441.

    Google Scholar 

  • Popat, K. M., Anand, P. S. and Dasare, B. D.: 1994, ‘Selective Removal of Fluoride Ion from Water by the Aluminum Form of the Aminomethylphosphonic Acid-type Ion Exchanger’, Reac. Polym. 23(1), 23–32.

    Google Scholar 

  • Tokunaga, S., Haron, M. J., Wasay, S. A., Wong, K. F., Laosangthum, K. and Uchiumi, A.: 1995, ‘Removal of Fluoride Ion from Aqueous Solutions by Multivalent Metal Compounds’, Int. J. Environ. Studies 48, 17–28.

    Google Scholar 

  • Wasay, S. A., Haron, M. J. and Tokunaga, S.: 1996a, ‘Adsorption of Fluoride, Phosphate and Arsenate Ions on Lanthanum-Impregnated Silica Gel’, Environ. Res. 68(3), 295–300.

    Google Scholar 

  • Wasay, S. A., Tokunaga, S. and Park, S. W.: 1996b, ‘Removal of Hazardous Anion from Aqueous Solutions by La(III)-and Y(III)-Impregnated Alumina’, Sep. Sci. Technol. 31(10), 1501–1514.

    Google Scholar 

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Correspondence to Young Ku.

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Ku, Y., Chiou, HM. The Adsorption of Fluoride Ion from Aqueous Solution by Activated Alumina. Water, Air, & Soil Pollution 133, 349–361 (2002). https://doi.org/10.1023/A:1012929900113

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