Abstract
Paleozoic black shales of the Saxothuringikum (Germany) with an average Corg. -content of 0.01 to 20 mass% were investigated with regard to the nature of organic matter. A special pyrolysis technique (DEGAS) was used for a temperature resolved analysis of different hydrocarbons (HC) and the simultaneous detection of inorganic volatiles during heating under vacuum up to 1450°C. The presented data indicate three different forms of organic matter occurring in the investigated black shales (bitumen, kerogen and pyrobitumen). Finally the influence of an igneous dyke intrusion on the alteration of the organic matter was examined.
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Schmidt, C.M., Heide, K. Thermal Analysis of Hydrocarbons in Paleozoic Black Shales. Journal of Thermal Analysis and Calorimetry 64, 1297–1302 (2001). https://doi.org/10.1023/A:1011530020564
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DOI: https://doi.org/10.1023/A:1011530020564