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Structures of Metal Complexes with Anions of Di(hydroxymethyl)phosphinic and Di(chloromethyl)phosphinic Acids

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Abstract

This paper considers the structural features of complexes containing Ag(I), 3dmetals (Cu and Ni), and rare-earth elements (REE) such as La, Nd, Er, and Lu, alkaline-earth (Sr) or alkaline (Li, Na) metals with anions of di(hydroxymethyl)phosphinic (L1) or di(chloromethyl)phosphinic (L2) acids with a general formula RR"PO– 2, where R = R" = OH and Cl for L1and L2, respectively. Different patterns of coordination between organophosphorus acids and different metals (four for each L1and L2) are described. Structures of copper(II) complexes with L1and L2were compared with those of Cu(II) with dialkyl- and diaryl-substituted monophosphonic and aminophosphinic acids.

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  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 117907, Russia

    V. S. Sergienko & G. G. Aleksandrov

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  1. V. S. Sergienko
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  2. G. G. Aleksandrov
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Sergienko, V.S., Aleksandrov, G.G. Structures of Metal Complexes with Anions of Di(hydroxymethyl)phosphinic and Di(chloromethyl)phosphinic Acids. Russian Journal of Coordination Chemistry 27, 324–340 (2001). https://doi.org/10.1023/A:1011398129852

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