Skip to main content
SpringerLink
Log in

X-Ray and X-ray Photoelectron Spectroscopy Studies of the Electronic Structure of Borane Derivatives

  • Published:
Journal of Structural Chemistry Aims and scope Submit manuscript

Abstract

This paper reviews the results of electronic structure studies of a number of typical members of borane series by X-ray and X-ray photoelectron spectroscopy using quantum chemical calculations. Fragment analysis of the molecular orbital structure is given. The nature of chemical interaction in boron cluster compounds is studied on models: simple molecules NH3, BH3, and BF3 and their adducts NH3⋅BH3 and NH3⋅BF3⋅. The electronic structure of B10H12L2 type compounds with Lewis bases L = NH3, (CH3)2S, (C6H5)3P is analyzed. The complexes are considered in terms of the concept of donor–acceptor interactions between the fragments. The donor–acceptor bond has contributions from both occupied and vacant acceptor orbitals. X-ray photoelectron data on the charged states of atoms in the compounds are overviewed. Electron distribution in complex compounds with transition metals [(1,2-B9C2H11)2M]–, M = FeIII, CoIII, NiIII, and NiIV and chain type polycobaltocarborane anions {[(3)-1,2-B9C2H11]2Co n [(3,6)-1,2-B8C2H10]n-1}n–, n = 2-7, is considered.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. T. A. Halgren, D. A. Kleier, J. H. Hall, et al., J. Am. Chem. Soc., 100, No. 21, 6595-6608 (1978).

    Google Scholar 

  2. J. H. Hall, Jr., D. A. Dixon, D. A. Kleier, et al., ibid., 97, No. 15, 4202-4213 (1975).

    Google Scholar 

  3. D. A. Dixon, D. A. Kleier, T. A. Halgren, and W. N. Lipscomb, ibid., 96, No. 7, 2293-2295 (1974).

    Google Scholar 

  4. R. B. King, Izv. Ross. Akad. Nauk, Ser. Khim., No. 8, 1353-1360 (1993).

    Google Scholar 

  5. K. Wittel and S. P. McGlynn, Chem. Rev., 77, No. 5, 745-771 (1977).

    Google Scholar 

  6. D. S. Urch and L. N. Mazalov, Chem. Brit., 30, No. 10, 832-835 (1994).

    Google Scholar 

  7. A. Meisel, H. Leonhardt, and R. Szargan, X-Ray Spectra and Chemical Bonding [in Russian], Naukova Dumka, Kiev (1981).

    Google Scholar 

  8. L. N. Mazalov, V. D. Yumatov, V. V. Murakhtanov, et al., X-Ray Spectra of Molecules [in Russian], Nauka, Novosibirsk (1977).

    Google Scholar 

  9. L. N. Mazalov and V. D. Yumatov, Electronic Structure of Extractants [in Russian], Nauka, Novosibirsk (1984).

    Google Scholar 

  10. G. G. Furin, A. V. Zibarev, L. N. Mazalov, and V. D. Yumatov, Electronic Structure of Fluoroorganic Compounds [in Russian], Nauka, Novosibirsk (1988).

    Google Scholar 

  11. T. M. Zimkina and A. S. Vinogradov, Izv. Akad. Nauk SSSR, Ser. Fiz., 36, No. 2, 248-254 (1972).

    Google Scholar 

  12. A. P. Sadovskii and L. I. Nasonova, Zh. Strukt. Khim., 18, No. 4, 673-676 (1977).

    Google Scholar 

  13. V. D. Yumatov, V. V. Murakhtanov, V. V. Volkov, et al., Zh. Neorg. Khim., 40, No. 1, 131-138 (1995).

    Google Scholar 

  14. V. A. Fomichev, Fiz. Tverd. Tela, 9, No. 11, 3167-3171 (1967).

    Google Scholar 

  15. M. S. Nakhmanson and V. I. Baranovskii, Teor. Éksp. Khim., 7, No. 1, 15-21 (1971).

    Google Scholar 

  16. S. V. Nekipelov, V. N. Akimov, and A. S. Vinogradov, Opt. Spektrosk., 64, No. 4, 817-821 (1988).

    Google Scholar 

  17. E. Ishiguro, S. Iwata, Y. Suzuki, et al., J. Phys. B: Atom. Mol. Phys., 15, No. 12, 1841-1854 (1982).

    Google Scholar 

  18. 18. K.-H. Hallmeier, R. Szargan, A. Meisel, et al., Spectrochim. Acta, 37A, No. 12, 1049-1053 (1981).

    Google Scholar 

  19. W. H. E. Schwarz, L. Mensching, K. H. Hallmeier, and R. Szargan, Chem. Phys., 82, Nos. 1/2, 57-65 (1983).

    Google Scholar 

  20. A. P. Hitchcock and D. C. Mancini, J. Electron. Spectrosc. Relat. Phenom., 67, No. 1, 1-132 (1994).

    Google Scholar 

  21. J. Arber and D. S. Urch, International Conference on X-Ray and Inner-Shell Processes in Atoms, Molecules, and Solids, Abstracts, Part 1, Leipzig (1984), pp. 17-18.

  22. N. T. Kuznetsov (ed.), Inorganic Hydride Chemistry [in Russian], Nauka, Moscow (1990), pp. 67-81.

    Google Scholar 

  23. V. D. Yumatov, E. A. Il'inchik, V. V. Murakhtanov, et al., Zh. Neorg. Khim., 38, No. 3, 423-427 (1993).

    Google Scholar 

  24. V. D. Yumatov, V. V. Murakhtanov, V. V. Volkov, et al., ibid., 43, No. 10, 1677-1682 (1998).

    Google Scholar 

  25. V. D. Yumatov, E. A. Il'inchik, V. V. Murakhtanov, et al., 29th Colloquium Spectroscopicum Internationale. Book of Abstracts, Leipzig (1995), p. 409.

  26. V. V. Volkov, E. A. Il'inchik, G. F. Khudorozhko, et al., Izv. Akad. Nauk, Ser. Khim., No. 10, 2248-2254 (1985).

    Google Scholar 

  27. V. V. Murakhtanov, T. M. Polyanskaya, and V. V. Volkov, Zh. Strukt. Khim., 37, No. 4, 652-663 (1996).

    Google Scholar 

  28. L. N. Mazalov, V. V. Volkov, S. Ya. Dvurechenskaya, and L. I. Nasonova, Zh. Neorg. Khim., 23, No. 7, 1640-1643 (1982).

    Google Scholar 

  29. V. V. Volkov, E. A. Il'inchik, L. N. Mazalov, et al., Izv. Akad. Nauk SSSR, Ser. Khim., No. 7, 1640-1643 (1982).

    Google Scholar 

  30. V. I. Nefedov, X-Ray Photoelectron Spectroscopy of Chemical Compounds. Handbook [in Russian], Khimiya, Moscow (1984).

    Google Scholar 

  31. D. N. Hendrickson, J. M. Hollander, and W. L. Jolly, Inorg. Chem., 9, No. 3, 612-615 (1970).

    Google Scholar 

  32. D. A. Allison, G. Johansson, C. J. Allan, et al., J. Electron. Spectrosc. Relat. Phenom., 1, No. 2, 269-283 (1972/73).

    Google Scholar 

  33. W. M. Riggs, Anal. Chem., 44, No. 4, 830-832 (1972).

    Google Scholar 

  34. L. O. Pont, A. R. Siedle, M. S. Lazarus, and W. L. Jolly, Inorg. Chem., 13, No. 2, 483 (1974).

    Google Scholar 

  35. H. Von Binder, E. Fluck, S. Hermanek, and J. Plesek, Z. Anorg. Allg. Chem., 433, 26-34 (1977).

    Google Scholar 

  36. K. Kimura, S. Katsumata, Y. Achiba, et al., Handbook of HeI Photoelectron Spectra of Fundamental Organic Molecules, Japan Scientific Societies Press, Tokyo (1981).

    Google Scholar 

  37. W. L. Jolly, K. D. Bomben, and C. J. Eyermann, Atom. Data Nucl. Data Tables, 31, No. 3, 433-493 (1984).

    Google Scholar 

  38. V. N. Akimov, A. S. Vinogradov, and A. V. Zhadenov, Opt. Spektrosk., 65, No. 2, 349-353 (1988).

    Google Scholar 

  39. H. Hosoya, K. Morokuma, S. Yamabe, et al., J. Mol. Struct. (Theochem), 71, No. 1, 1-281 (1991).

    Google Scholar 

  40. D. R. Lloyd and N. Lynaugh, J. Chem. Soc., Faraday Trans. II, 68, No. 6, 947-958 (1972).

    Google Scholar 

  41. V. V. Murakhtanov, Zh. Strukt. Khim., 33, No. 5, 14-19 (1992).

    Google Scholar 

  42. V. D. Yumatov, V. V. Murakhtanov, N. F. Salakhutdinov, et al., Zh. Strukt. Khim., 28, No. 5, 73-80 (1987).

    Google Scholar 

  43. J. N. Francis and M. F. Hawthorne, Inorg. Chem., 10, No. 4, 863-864 (1971).

    Google Scholar 

  44. D. A. Brown, M. O. Fanning, and N. J. Fitzpatrick, ibid., 17, No. 6, 1620-1623 (1978).

    Google Scholar 

  45. R. J. Wiersema and M. F. Hawthorne, J. Am. Chem. Soc., 96, No. 3, 761-769 (1974).

    Google Scholar 

  46. R. N. Grimes (ed.), Metal Interactions with Boron Clusters, Plenum, New York (1982), pp. 24, 241.

    Google Scholar 

  47. W. H. Knoth, H. C. Miller, J. C. Sauer, et al., Inorg. Chem., 3, No. 2, 159-167 (1964).

    Google Scholar 

  48. R. D. Dobrott and W. N. Lipscomb, J. Chem. Phys., 37, No. 8, 1779-1784 (1962).

    Google Scholar 

  49. E. A. Il'inchik, V. V. Volkov, O. V. Volkov, et al., “Comparative studies of the electronic structure of borane and thioborane clusters,” Preprint No. 90-05, Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences (1990).

  50. E. Cartmell and G. W. A. Fowles, Valency and Molecular Structure, Butterworths, London (1977).

    Google Scholar 

  51. E. A. Il'inchik, V. V. Volkov, and O. V. Volkov, Zh. Strukt. Khim., 40, No. 2, 358-371 (1999).

    Google Scholar 

  52. S. Ya. Dvurechenskaya, V. V. Volkov, I. I. Gorbacheva, and N. D. Krivosheeva, Izv. Sib. Otd. Akad. Nauk SSSR, Ser. Khim. Nauk, 1, No. 2, 74-80 (1983).

    Google Scholar 

  53. J. N. Murrell, S. F. A. Kettle, and J. M. Tedder, Valence Theory Wiley, New York (1965).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Siberian Branch, Russian Academy of Sciences, Institute of Inorganic Chemistry, Russia

    V. D. Yumatov, E. A. Il'inchik, L. N. Mazalov, O. V. Volkov & V. V. Volkov

Authors
  1. V. D. Yumatov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. E. A. Il'inchik
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. L. N. Mazalov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. O. V. Volkov
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. V. V. Volkov
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Yumatov, V.D., Il'inchik, E.A., Mazalov, L.N. et al. X-Ray and X-ray Photoelectron Spectroscopy Studies of the Electronic Structure of Borane Derivatives. Journal of Structural Chemistry 42, 281–295 (2001). https://doi.org/10.1023/A:1010515402114

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1010515402114

Keywords

Search

Navigation