Abstract
Oxidative deoximination of aldoximes and ketoximes by pyridium fluorochromate proceeds by nucleophilic attack of the chromate oxygen on the oxime carbon to give a cyclic intermediate in the rate-determining step.
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Bhandari, A., Mishra, P. & Banerji, K.K. Kinetics and Mechanism of the Oxidative Regeneration of Carbonyl Compounds from Oximes by Pyridinium Fluorochromate. Reaction Kinetics and Catalysis Letters 71, 343–347 (2000). https://doi.org/10.1023/A:1010391529810
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DOI: https://doi.org/10.1023/A:1010391529810