Skip to main content
SpringerLink
Log in

Kinetics and Mechanism of the Thermal Decomposition of M(NO3)2·nH2O (M=Cu, Co, Ni)

  • Published:
Journal of Thermal Analysis and Calorimetry Aims and scope Submit manuscript

Abstract

This paper presents the results of simultaneous DTA-TG-DTG and DSC studies on the thermal decomposition of Cu(NO3)2·3H2O, Co(NO3)2·6H2O and Ni(NO3)2·6H2O in an air atmosphere. The mechanism and enthalpies of the investigated processes were determined, as well as the kinetic parameters of the processes run under non-isothermal conditions by means of Kissinger's method. The dependence of the activation energy on the ionic radius of the cations building up the crystal lattices of the investigated compounds was also studied.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. W. W. Wendlandt, Anal. Chim. Acta, 15 (1956) 435.

    Article  CAS  Google Scholar 

  2. W. W. Wendlandt and J. L. Bear, J. Inorg. Nucl. Chem., 12 (1960) 276.

    Article  CAS  Google Scholar 

  3. M. Dabkowska and A. Broniszewska, Annales Univ. Mariae Curie Skłodowska, Lublin Sectio, AA 28 (1973) No12.

  4. M. Dabkowska, Annales Univ. Mariac Curie Skłodowska, Lublin Scctio, AA 29 (1974) No5.

  5. D. M. Dvornikova, W. P. Sevostianov and N. M. Ambrozhii, Zh. Neorg. Khim., 14 (1969) 2325.

    CAS  Google Scholar 

  6. D. M. Chizikov, B. N. Rabinovich and E. H. Subbotina, Zh. Neorg. Khim., 10 (1965) 2527.

    Google Scholar 

  7. G. Liptay, Atlas of Thermoanalytical Curves, Akadémiai Kiadó, Budapest 1976.

    Google Scholar 

  8. R. Gajerski, S. Labus, A. Malecki and K. T. Wojciechowski, Proc. CETTA'97, Zakopane 8–13 September 1997, Abstracts, p. 309.

  9. K. T. Wojcicchowski, R. Gajerski, S. Labus and A. Malecki, Proc. CETTA'97, Zakopane 8–13 September 1997, Abstracts, p. 79.

  10. K. T. Wojcicchowski, R. Gajerski, S. Labus and A. Malecki, Proc. CETTA'97, Zakopane 8–13 September 1997, Abstracts, p. 80.

  11. H. E. Kissinger, Anal. Chem., 29 (1957) 1702.

    Article  CAS  Google Scholar 

  12. A. Kelly and G. W. Growes, Crystallography and Crystal Defects, Longman, London 1970, p. 472

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Technical Faculty, University of Belgrade, 19210, Bor, Yugoslavia

    Ž. D Živković, D. T. Živković & D. B. Grujičić

Authors
  1. Ž. D Živković
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. D. T. Živković
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. D. B. Grujičić
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Živković, Ž.D., Živković, D.T. & Grujičić, D.B. Kinetics and Mechanism of the Thermal Decomposition of M(NO3)2·nH2O (M=Cu, Co, Ni). Journal of Thermal Analysis and Calorimetry 53, 617–623 (1998). https://doi.org/10.1023/A:1010170231923

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1010170231923

Search

Navigation