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Molecular structure of Al0.916Cr0.084(acac)3

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Abstract

The molecular structure of a solid solution of Al(acac)3 and Cr(acac)3 has been determined. The Al:Cr ratio as determined by refinement of occupancy and anisotropic displacement parameters was determined to be 91.6:8.4%. The unit cell parameters for Al0.916Cr0.084(acac)3 are smaller and the M-O distances are intermediate compared to those in the pure compounds, Crystal data: monoclinic, P21/c, a = 13.989(3), b = 7.539(2), c = 16.307(3) Å, β = 98.82(3)°, V = 1699.6(6), Z = 4.

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References

  1. See for example: (a) Bradley, D.C. Chem. Rev. 1989, 89, 1317. (b) Girolami, G.S.; Gozum, J.E. Mater. Res. Soc. Symp. Proc. 1990, 168, 319. (c) Ajayi, O.B.; Akanni, M.S.; Lambi, J.N.; Jeynes, C.; Watts, J.F. Thin Solid Films 1990, 185, 123. (d) Maruyama, T.; Arai, S. Appl. Phys. Lett. 1992, 60, 322. (e) Tonge, L.M.; Richeson, D.S.; Marks, T.J.; Zhao, J.; Wessels, B.W.;Marcy, H.O.;Kannewurf, C.R. Electron Transfer in Biology and the Solid State: Inorganic Compounds with Unusual Properties, Part III. In ACS Advances in Chemistry Series 1990, 226, 351; Johnson, M.K.; King, R.B.; Kurtz, D.M., Jr.; Kutal, C.;Norton, M.L.; Scott, R.A.,Eds. American Chemical Society: Washington, DC, 1990. (f) Haga, K.; Katahira, F.; Watanabe, H. Thin Solid Films 1999, 343–344, 145. (g) Maruyama, T.; Ikuta, Y. J. Mater. Sci. 1993, 28, 5073. (h) Condorelli, G.G.; Malandrino, G.; Fragala, I. Chem. Mater. 1994, 6, 1861.

    Google Scholar 

  2. β-diketonate complexes are commercially available for over forty metals; see Aldrich Chemical Co., Milwaukee, WI 53201;Gelest, Inc., 612 William Leigh Dr., Tullytown, PA 19007; Strem Chemicals, 7 Mulliken Way, Dexter Industrial Park, Newburyport, MA 01950, Danvers, MA.

  3. Fahlman, B.D.; Barron, A.R., submitted for publication.

  4. Mason, M.R.; Smith, J.M.; Bott, S.G.; Barron, A.R. J. Am. Chem. Soc. 1993, 115, 4971.

    Google Scholar 

  5. Sheldrick, G.M. Acta Crystallogr. 1990, A46, 467.

    Google Scholar 

  6. Hon, P.K.; Pfluger, C.E. J. Coord. Chem. 1973, 3, 67.

    Google Scholar 

  7. Morosin, B. Acta Crystallogr. 1965, 19, 131.

    Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, Rice University, Houston, Texas, 77005

    Bradley D. Fahlman & Andrew R. Barron

  2. Department of Chemistry, University of Houston, Houston, Texas, 77204

    Simon G. Bott

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  1. Bradley D. Fahlman
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  2. Simon G. Bott
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  3. Andrew R. Barron
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Fahlman, B.D., Bott, S.G. & Barron, A.R. Molecular structure of Al0.916Cr0.084(acac)3. Journal of Chemical Crystallography 30, 65–67 (2000). https://doi.org/10.1023/A:1009554301560

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