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Crystal Structures of Dibenzo-13-crown-4 and sym-(2-Picolyloxy)dibenzo-13-crown-4

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Abstract

Solid-state structures are determined for two compounds which containdibenzo-13-crown-4 rings. These include the parent crown etherdibenzo-13-crown-4 and its lariat ether derivativesym-(2-picolyloxy)dibenzo-13-crown-4. The solid-state structure ofdibenzo-13-crown-4 is complicated by disorder of the carbon atoms in theethylene and propylene bridges. The asymmetric unit of the crystal for thelariat ether derivative consists of two chemically identical, butcrystallographically different, molecules.

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Authors and Affiliations

  1. Department of Chemistry and Biochemistry, Brigham Young University, Provo, Utah, 84602, U.S.A

    N. Kent Dalley, Uriel Olsher & Xiaolan Kou

  2. Department of Chemistry and Biochemistry, Texas Tech University, Lubbock, Texas, 79409, U.S.A

    Richard A. Bartsch & Jong Chan Lee

Authors
  1. N. Kent Dalley
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  2. Uriel Olsher
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  3. Xiaolan Kou
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  4. Richard A. Bartsch
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  5. Jong Chan Lee
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Dalley, N.K., Olsher, U., Kou, X. et al. Crystal Structures of Dibenzo-13-crown-4 and sym-(2-Picolyloxy)dibenzo-13-crown-4. Journal of Inclusion Phenomena 29, 309–321 (1997). https://doi.org/10.1023/A:1007936304054

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  • DOI: https://doi.org/10.1023/A:1007936304054

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