Abstract
The glass-forming region of the BiO1.5—PbO—CuO system has been determined by the melt-quenching technique. The glass transition temperatures, Tg, and the first crystallization peak temperatures, Tx1, are around 240°C and 285°C, respectively. The glass structure consists of [BiO3] and [BiO6] units, and the conversion between these polyhedra mainly depends on the CuO and PbO content. The covalent characteristic in the infrared absorption spectra of the [PbOn] pyramidal units becomes significant when the glass contains more PbO.
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Hu, Y., Liu, NH. & Lin, UL. Glass formation and glass structure of the BiO1.5—PbO—CuO system. Journal of Materials Science 33, 229–234 (1998). https://doi.org/10.1023/A:1004382721435
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DOI: https://doi.org/10.1023/A:1004382721435