Abstract
The oxidative methylation of toluene with methane is used as a test reaction for determining the activity, selectivity and yield of C8 hydrocarbons (ethylbenzene and styrene) over different zeolite and zeolite-type catalysts, viz., X, Y, mordenite, ZSM-5, silicalite and AlPO4-5. Selectivity and basicity increase with decreasing Si/Al atomic ratio within the series of the same structural type. The basicity, surface structure and structural integrity are characterized by TPD of CO2, XPS and IRS, respectively.
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Kovacheva, P., Arishtirova, K. & Predoeva, A. Basic zeolite and zeolite-type catalysts for the oxidative methylation of toluene with methane. Reaction Kinetics and Catalysis Letters 79, 149–155 (2003). https://doi.org/10.1023/A:1024176121544
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DOI: https://doi.org/10.1023/A:1024176121544