Abstract
Metastable triplet helium molecules, created in helium nanodroplets by electron bombardment, become trapped in surface states. Photo induced electronic transitions of a molecule result in its detachment from the cluster. It is subsequently detected when it emits a secondary electron upon reaching a nearby surface. We have found that there are two different characteristic energies with which the molecules are emitted, one thermal and one much larger. We have also found that the spectral lines are asymmetric, but the peaks are only slightly blue shifted from their values in the free molecule.
Similar content being viewed by others
REFERENCES
Proceedings of the 128th WE-Heraeus-Seminar on Ions and Atoms in Superfluid Helium, edited by H. Gunther et al., Z. Phys B, 98,No.3 (1995)
J. Gspann, in Physics of Electronic and Atomic Collisions, edited by S. Datz, (North Holland, Amsterdam, 1982), p. 79
J. Gspann, and H. Vollmar, J. Chem. Phys., 73, 1657 (1980)
H. Buchenau, et al., J. Chem. Phys., 92, 6875 (1990); M. Hartmann et al., Phys. Rev. Lett., 76, 4560 (1996); S. Grebenev, J. P. Toennies, and A. F. Vilesov, Science, 279, 2083 (1998) and references therein
H. Buchenau, J. P. Toennies, and J. A. Northby, J. Chem. Phys., 95, 8134(1991)
S. Goyal, D. L. Schutt, and G. Scoles, Phys. Rev. Lett., 69, 933 (1992)
F. Stienkemeier et al., Z. Phys. D, 38, 253 (1996), and private communication
T. Jiang, and J. A. Northby, Phys. Rev. Lett., 68, 2620 (1992)
M. Joppien, R. Karnbach, and T. Möller, Phys. Rev. Lett., 71, 2654 (1993)
R. Mehrotra, E. K. Mann, and A. J. Dahm, J. Low Temp. Phys., 36, 47 (1979)
J. W. Keto et al., Phys. Rev. A, 10, 872 (1974)
J. A. Northby, S. Yurgenson, and C. Kim, J. Low Temp. Phys., 101, 427 (1995)
T. Jiang, S. Sun, and J. A. Northby, Physics and Chemistry of Finite Systems: From Clusters to Crystals, vol. I, edited by P. Jena et al., (Kluwer Academic Pub., Netherlands, 1992), p. 223
M. L. Ginter, J. Chem. Phys., 42, 561 (1965)
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Kim, C., Yurgenson, S., Hu, CC. et al. Photodetachment of Metastable Helium Molecules from the Surface of Helium Nanodroplets. Journal of Low Temperature Physics 113, 1097–1102 (1998). https://doi.org/10.1023/A:1022581123318
Issue Date:
DOI: https://doi.org/10.1023/A:1022581123318