Abstract
The mechanism of solid-phase reaction of Bi4Ti3O12 formation was studied. Formation of the layered perovskite-like bismuth titanate occurs via intermediates with sequential changes in the coordination polyhedron of bismuth. A correlation is analyzed between the temperature of the onset of activation of the solid-phase reaction and the melting point of the surface (intergrain) phase based on bismuth oxide.
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REFERENCES
Aurivillius, B., Ark. Kemi, 1949, vol. 1, no. 1, pp. 499–512.
Gusarov, V.V., Zh. Obshch. Khim., 1997, vol. 67, no. 12, pp. 1959–1964.
Burton, T.M., J. Solid State Chem., 1974, vol. 9, no. 2, pp. 173–175.
Wells, A.F., Structural Inorganic Chemistry, Oxford: Clarendon, 1986.
Buerger, M.J., Fortschr. Miner., 1961, vol. 39, pp. 9–24.
Harwing, H.A., Z. Anorg. Allgem. Chem., 1978, vol. 444, no. 7, pp. 151–166.
Craig, D.C. and Stephenson, N.C., J. Solid State Chem., 1975, vol. 15, no. 1, pp. 1–8.
Abrahams, S.C., Jamieson, P.B., and Bernstein, J.L., J. Chem. Phys., 1967, vol. 47, no. 10, pp. 4034–4041.
Rukovodstvo po rentgenostrukturnomu analizu (Manual on X–ray Diffraction Analysis), Frank–Kamenetskii, V.A., Ed., Leningrad: Nedra, 1975.
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Morozov, M.I., Mezentseva, L.P. & Gusarov, V.V. Mechanism of Formation of Bi4Ti3O12. Russian Journal of General Chemistry 72, 1038–1040 (2002). https://doi.org/10.1023/A:1020734312307
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DOI: https://doi.org/10.1023/A:1020734312307