Abstract
Swimmers and users of motor boats frequenting old, water-filled gravel pits in Kiiminki, Northern Finland, found in August 1993 that they were suffering from painful irritation of the eyes and that their boats had developed a finely polished surface on their aluminium hulls, evidently due to the corrosive action of the water. Subsequent measurements carried out by the water authority showed that the pH of the water in some of the pits was extremely low, reaching a value of 3.4 at its lowest. To find out the causes of the abnormally low pH values, the present authors began systematic measurements of the pH and determination of the chemical composition (Si, Al, Ca, Mg, K, Na, Fe, Mn, Cu, Pb, Ni, Cd, Cl-, NO3 -, SO4 2-) of the water in 23 gravel pits. In addition, a series of laboratory experiments was carried out to examine the interaction of water with samples of the soil and bedrock of the area to evaluate the role of this process as a possible cause of the acidification. The results show that the reaction of water with the moderately to intensively weathered sulphide and jarosite-bearing black schists, typical of the bedrock of the area, can bring about aqueous solutions similar in pH and sulphate--nitrate ratios to those found naturally in the gravel pits. The contribution of other possible mechanisms, e.g. acidic precipitation as such or combined with enhanced evaporation, the possible use of the pits as dumping sites for acidic waste or the flow or seepage of acidic peat-bog waters into the pits from the surrounding wetlands, cannot be ruled out entirely, but their contribution seems to be of minor importance. Since the concentrations of several heavy metals (notably Pb, Cd, Ni, Fe and Mn) and of sulphate and aluminium has increased in the pit water as a result of the acidification process and exceed the norms laid down in the EU Drinking Water Directive, acidification of water in gravel pits due to the oxidation of sulphides must be regarded as a new, serious environmental and geomedical threat which has so far remained poorly known or unrecognised.
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References
Aario, R. 1971. Syndepositional deformation in the Kurkiselkä esker, Kiiminki, Finland. Bulletin of the Geological Society of Finland, 43, 163–172.
Alpers, C.N. and Blowes, D.W. (eds.) 1994. Environmental Geochemistry of Sulfide Oxidation. ACS Symposium Series. No. 550. American Chemical Society, Washington, DC.
Bierens De Haan, S., Rae, J.E. and Parker, A. 1994. Pyrite oxidation in the Tertiary sands of the London Basin aquifer. Applied Geochemistry, 9, 161–173.
Borek, S.L. 1994. Effect of humidity on pyrite oxidation. In: Alpers, C.N. and Blowes, D.W. (eds.), Environmental Geochemistry of Sulfide Oxidation, ACS Symposium Series No. 550, pp. 31–44. American Chemical Society, Washington, DC.
Chapman, M.M., Jones, D.R. and Jung, R.F. 1983. Processes controlling metal ion attenuation in acid mine drainage streams. Geochimica et Cosmochimica Acta, 47, 1957–1973.
Cravotta, C.A., III 1994. Secondary iron-sulfate minerals as sources of sulfate and acidity: geochemical evolution of acidic ground water at a reclaimed surface coal mine in Pennsylvania. In: Alpers, C.N. and Blowes, D.W. (eds.), Environmental Geochemistry of Sulfide Oxidation, ACS Symposium Series 550, pp. 345–364. American Chemical Society, Washington, DC.
Eronen, M. 1983. Late Weichselian and Holocene shore displacement in Finland. In: Smith, D.E. and Dawson, A.G. (eds.), Shorelines and Isostasy, Institute of British Geographers Special Publication No. 16, 183–207. Academic Press, London.
Faure, G. 1991. Principles and Applications of Inorganic Geochemistry. Macmillan, New York.
Ferris, F.G., Tazaki, K. and Fyfe, W.S. 1989. Iron oxides in acid mine drainage environments and their associated bacteria. Chemical Geology, 74, 321–330.
Fuge, R., Pearce, F.M., Pearce N.J.G. and Perkins, W.T. 1994. Acid mine drainage in Wales and influence of ochre precipitation on water chemistry. In: Alpers, C.N. and Blowes, D.W. (eds.), Environmental Geochemistry of Sulfide Oxidation. ACS Symposium Series No. 550. pp. 261–275. American Chemical Society, Washington, DC.
Gray, N.F. 1994. Drinking Water Quality: Problems and Solutions. John Wiley
Hatva, T. 1994. ‘soranoton vaikutus pohjaveteen’-tutkimusprojektin päätulokset. In: Korhonen, M. (ed.), Maa-ainesten otto ja pohjavesi. Teemapäivä 1994, pp. 5–14. Vesiyhdistys, Helsinki.
Hatva, T., Hyyppä, J., Ikäheimo, J., Penttinen, H. and Sandborg, M. 1993a. Soranoton vaikutus pohjaveteen. Raportti V. Soranotto ja pohjaveden suojelu. Vesi-ja ympäristöhallituksen Julkaisuja B, 15, 1–120.
Hatva, T., Hyyppä, J., Ikäheimo, J., Penttinen, H. and Sandborg, M. 1993b. Soranoton vaikutus pohjaveteen. Raportti: pohjavesi ja soranotto. Ympäristöministeriö, Kaavoitus-ja rakennusosasto. Tutkimusraportti, 1/1994, 1–58.
Helovuori, O. 1979. Geology of the Pyhäsalmi ore deposit. Economic Geology, 74 1084–1101.
Honkamo, M. 1987. Geochemistry and tectonic setting of Early Proterozoic volcanic rocks in Northern Ostrobothnia, Finland. In: Pharaoh, T.C., Beckinsdale, R.D. and Rickard, D.T. (eds.), Geochemistry and Mineralization of Proterozoic Volcanic Suites. A Special Publication of the Geological Society of London, pp. 59–68. Geological Society, London.
Honkamo, M. 1988. Haukiputaan ja Kiimingin karttaalueiden kallioperä. Summary: Pre-Quaternary rocks of the Haukipudas and Kiiminki map-sheet areas. Suomen geologinen kartta 1:100 000, Geological Map of Finland 1:100 000. Kallioperäkartan selitykset, Explanation to the Map of Rocks. Geologian tutkimuskeskus, Geological Survey of Finland, Espoo.
Howells, G. 1990. Acid Rain and Acid Waters. Horwood, Chichester.
Hyyppä, J. and Penttinen, H. 1993a. Soranoton vaikutus pohjaveteen. Tutkimusraportti II, alueelliset pohjavesitutkimukset. Osa A. Tutkimustulokset. Vesi-ja ympäristöhallituksen Monistesarja, 329, 1–231.
Hyyppä, J. and Penttinen, H. 1993b. Soranoton vaikutus pohjaveteen. Tutkimusraportti II, alueeliset tutkmukset. Osa B. Tutkimustulosten tarkastelu ja johtopäätökset. Vesi-ja ympäristöhallituksen Monistesarja, 329, 1–143.
Järvinen, O. and Vänni, T. 1994. Sadeveden pitoisuus ja laskeuma-arvot Suomessa vuonna 1993. Vesi-ja ympäristöhallituksen monistesarja, 579 1–68.
Kauppi, P., Anttila, P. and Kenttämies, K. (eds.) 1990. Acidification in Finland. Springer Verlag, Berlin.
Kennedy, I.R. 1986. Acid Rain and Acid Soil. J. Wiley, New York.
Kuusinen, K. 1993. Soranoton vaikutus pohjaveteen. Tutkimusraportti IV. Mikrobien kulkeutuminen maaperässä ja pohjavedessä. Vesi-ja ympäristöhallituksen monistesarja, 331, 1–73.
Lahermo, P., Ilmasti, M., Juntunen, R. and Taka, M. 1990. The Geochemical Atlas of Finland, Part 1. The Hydrogeochemical Mapping of Finnish Groundwater. Geological Survey of Finland, Espoo.
Lapakko, K. and Antonson, D.A. 1994. Oxidation of sulfide minerals present in Duluth Complex rock: a laboratory study. In: Alpers, C.N. and Blowes, D.W. (eds.) Environmental Geochemistry of Sulfide Oxidation, ACS Symposium Series No. 550, pp. 593–607. American Chemical Society, Washington, D.C.
Leppäjärvi, R. (ed.) 1992. Hydrological Yearbook of Finland 1989. Vesi-ja Ympäristöhallitus, Helsinki.
Loukola-Ruskeeniemi, K. 1992. Metalliferous black shales — a probable source of mercury in pike in Lake Kolmisoppi, Sotkamo, Finland. Bulletin of the Geological Society of Finland, 62, 167–175.
Lowson, R.I. 1982. Aqueous oxidation of pyrite by molecular oxygen. Chemical Reviews, 82, 461–497.
McCormick, J. 1990. Acid Earth: The Global Threat of Acid Pollution, 2nd edition. Earthscan Publications, London, 255p.
McKibben, M.A. and Barnes, H.L. 1986. Oxidation of pyrite in low temperature acidic solutions; rate laws and surface textures. Geochimica and Cosmochimica Acta, 50, 1509–1520.
Moses, C.O. and Herman, J.S. 1991. Pyrite oxidation at circumneutral pH. Geochimica et Cosmochimica Acta, 55, 471–482.
Moses, C.O., Nordstrom, D.K., Herman, J.S. and Mills, A.L. 1987. Aqueous pyrite oxidation by dissolved oxygen and by ferric iron. Geochimica et Cosmochimica Acta, 51, 1561–1571.
Nordstrom, D.K. and Munoz, J.L. 1985. Geochemical Thermodynamics, p. 299. Blackwell Scientific Publications, Boston.
Palko, J. 1994. Acid sulphate soils and their agricultural and environmental problems in Finland. Acta Universitatis Ouluensis, ser. C 75.
Piispanen, R. 1983. Trace element geochemistry as a guide to mineral deposits associated with Precambrian granites in Northern Finland. Institute of Geosciences and Astronomy University of Oulu. Unpublished manuscript, 36p.
Pratt, A.R., Nesbitt, H.W. and Muir, I.J. 1994. Generation of acids from mine waste: oxidative leaching of pyrrhotite in dilute H2SO4 solutions at pH 3.0. Geochimica et Cosmochimica Acta, 58, 5147–5159.
Reichenbach, I. 1994. Black shale as an environmental hazard: a review of black shales in Canada. Geological Survey of Canada, Open File 2697, 1–61.
Reuss, J.O. and Johnson, D.W. 1986. Acid Deposition and the Acidification of Soils and Waters. Springer-Verlag, New York.
Saarnisto, M. 1981. Holocene emergence history and stratigraphy in the area north of the Gulf of Bothnia. Annales Academiae Scientiarum Fennicae, ser. A III Geologica-Geographica, 130, 1–42.
Sandborg, M. 1993a. Soranoton vaikutus pohjaveteen. Tutkimusraportti I. Pohjaveden laatuun vaikuttavien aineiden geokemiallisia ominaisuuksia. Vesi-ja ympäristöhallituksen Monistesarja, 328, 1–57.
Sandborg, M. 1993b. Soranoton vaikutus pohjaveteen. Tutkimusraportti III. Vajovesitutkimukset. Vesi-ja ympäristöhallituksen Monistesarja, 330, 1–127.
Steger, H.F. and Desjardins, L.E. 1978. Oxidation of sulfide minerals, 4. Pyrite, chalcopyrite and pyrrhotite. Chemical Geology, 23, 225–237.
Strömberg, B. and Banwart, S. 1994. Kinetic modelling of geochemical processes at the Aitik mining waste rock site in northern Sweden. Applied Geochemistry, 9, 583–595.
Sullivan, P.J., Yelton, J.L. and Reddy, K.J. 1988. Iron sulfide oxidation and the chemistry of acid generation. Environmental Geology and Water Science, 11, 289–295.
Suzuki, I., Chan, C.W. and Takeuchi, T.L. 1994. Oxidation of inorganic sulfur compounds by Thiobacilli. In: Alpers, C.N. and Blowes, D.W. (eds.), Environmental Geochemistry of Sulfide Oxidation, pp. 60–67. American Chemical Society, Washington, D.C.
Thurman, E.M. 1985. Organic Geochemistry of Natural Waters. Martinus Nijhoff/Dr. W. Junk Publishers, Dordrecht.
Tolonen, K. and Hosiaisluoma, V. 1978. chemical properties of surface water in Finnish ombrotrophic mire complexes with special reference to algal growth. Annales Botanici Fennici, 15, 55–72.
Vasunta, E. 1984. Jolosharju. Unpublished master's thesis. 92 p. Department of Geology, University of Oulu, Finland.
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Piispanen, R., Nykyri, T. Acidification of groundwater in water-filled gravel pits -- a new environmental and geomedical threat. Environmental Geochemistry and Health 19, 111–127 (1997). https://doi.org/10.1023/A:1018454622669
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DOI: https://doi.org/10.1023/A:1018454622669