Abstract
The main goal of chemical analytical monitoring in the destruction of chemical weapons is to identify highly toxic compounds of similar structures in long homologues series. The difficulties with the identification are due to a wide range of possible structures of such compounds with similar mass-spectral patterns. This necessitates the development of special approaches to the interpretation of analytical data. The paper presents the data of experimental studies of specific features of chromatographic–mass spectrometric behavior of 150 substances of the specified classes. The account of these data can improve the reliability of the identification.
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Kireev, A.F., Rybal'chenko, I.V., Savchuk, V.I. et al. Qualitative Chromatographic–Mass Spectrometric Analysis of Highly Toxic Alkyl Phosphonate and Alkyl Thiophosphonate Derivatives. Journal of Analytical Chemistry 57, 708–716 (2002). https://doi.org/10.1023/A:1016873825817
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DOI: https://doi.org/10.1023/A:1016873825817