Abstract
Platinum catalysts (0.003–0.52% Pt) based on leached sodium silicate and boron silicate fiberglass supports are studied in the complete oxidation of hydrocarbons (n-butane and propane) and high-temperature SO2 oxidation. It was shown that platinum localized in the bulk of the glass matrix show a higher activity and thermal stability than metal particles supported on the outer surface of fiberglass. The experimental results for hydrocarbon oxidation on platinum-containing fiberglass gauzes at short contact times are discussed.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
REFERENCES
Nicholas, D.M., Shah, Y.T., and Zlochower, I.A., Ind. Eng. Chem. Prod. Res. Dev., 1976, vol. 15, no. 1, p. 29.
Barelko, V.V., Khalzov, P.I., Zviagin, V.N., and Onischenko, V.Ya., Proc. 11 Conf. “Modern Trend in Chemical Kinetics and Catalysis,” Novosibirsk, 1995, vol. 2(1), p. 164.
Barelko, V.V., Yuranov, I.A., Cherashev, A.V., et al., Dokl. Ross. Akad. Nauk, 1998, vol. 361, no. 4, p. 485.
Kiwi-Minsker, L., Yuranov, I., Holler, V., and Renken, A., Chem. Eng. Sci., 1999, vol. 54, p. 4785.
Simonova, L.G., Barelko, V.V., Lapina, O.B., Paukshtis, E.A., Terskikh, V.V., Zaikovskii, V.I., and Bal'zhinimaev, B.S., Kinet. Katal., 2001, vol. 42, no. 5, p. 762.
Simonova, L.G., Barelko, V.V., Paukshtis, E.A., Lapina, O.B., Terskikh, V.V., Zaikovskii, V.I., and Bal'zhinimaev, B.S., Kinet. Katal., 2001, vol. 42, no. 6, p. 907.
Simonova, L.G., Barelko, V.V., Zaikovskii, V.I., Bukhtiyarov, V.I., Toktarev, A.V., and Bal'zhinimaev, B.S., Kinet. Katal., 2001, vol. 42, no. 6, p. 917.
Dentschman, O. and Schmidt, L., AIChE J., 1998, vol. 44, no. 11, p. 2465.
Popovskii, V.V., Sazonov, V.A., Chermoshentseva, G.K., Panarina, T.L., and Eliseeva, L.F., Trudy III Vsesoyuznoi konferentsii “Kataliticheskaya ochistka otkhodyashchikh gazov promyshlennykh predpriyatii i vykhlopnykh gazov avtotransporta” (Proc. III All-Union Conf. on the Catalytic Cleaning of Exhaust Gases of Industrial Enterprises and Automotive Exhaust Gases), Novosibirsk, 1981, p. 80.
Feltbouse, T.R., Berkel, D.A., Jost, S.R., Mc Grew, E.L., and Vavere, A., Advanced Catalysts and Nanostructured Material: Modern Synthetic Methods, Moser, W.R., Ed., New York: Academic, 1996, p. 91.
US Patent 5175136, 1992.
Simonova, L.G., Gritsenko, N.V., Dzis'ko, V.A., and Lapina, O.B., Kinet. Katal., 1987, vol. 28, no. 2, p. 454.
Boudart, M., Usp. Khim., 1974, vol. 43, no. 2, p. 317.
Bodke, A.S., Henning, D., Schmidt, L.D., Bharadwaj, S.S., Maj, J.J., and Siddall, J., J. Catal., 2000, vol. 191, p. 62.
O'Connor, R.P. and Schmidt, L.D., J. Catal., 2000, vol. 191, p. 245.
Quah, E.B.H., Mathews, J.F., and Li, Ch.-Zh., J. Catal., 2001, vol. 197, no. 2, p. 315.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Simonova, L.G., Barelko, V.V., Toktarev, A.V. et al. Catalysts Based on Fiberglass Support: IV. Platinum Catalysts Based on Fiberglass Support in Oxidation of Hydrocarbons (Propane and n-Butane) and Sulfur Dioxide. Kinetics and Catalysis 43, 61–66 (2002). https://doi.org/10.1023/A:1014249129178
Issue Date:
DOI: https://doi.org/10.1023/A:1014249129178