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Synthesis and crystal structure of [(PhenH)(PhenH2)][BiCl6]·2H2O with different o-phenanthroline protonations

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Abstract

The reaction between bismuthate oxide and phen (1,10-phenanthroline) in acid medium led to the isolation of the unusual [(PhenH)(PhenH2)][BiCl6]·2H2O derivative, which has been characterized by X-ray analysis and IR spectroscopy. The compound crystallizes in the triclinic space group \([\text[P\bar 1]]\) with a = 8.313(2), b = 9.349(2), c = 9.807(3) Å, α = 86.39(3), β = 110.27(3) and γ = 106.48(3)°. The crystal structure is made of [BiCl6]3− anions and [(PhenH)(PhenH2)]3+ cations. A network of hydrogen bond interactions involving the two clathrated water molecules, the phenanthroline moiety and the chlorines characterizes the entire structure.

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Authors and Affiliations

  1. ICTIMA - CNR, Corso Stati Uniti 4, 35127, Padova, Italy

    Franco Benetollo

  2. Istituto di Chimica Farmaceutica, Università di Milano, 20131, Milano, Italy

    Gabriella Bombieri

  3. Dipartimento di Chimica Inorganica, Università di Palermo, 90123, Palermo, Italy

    Giuseppe Alonzo, Nuccio Bertazzi & Girolamo A. Casella

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  1. Franco Benetollo
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  2. Gabriella Bombieri
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  3. Giuseppe Alonzo
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  4. Nuccio Bertazzi
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  5. Girolamo A. Casella
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Benetollo, F., Bombieri, G., Alonzo, G. et al. Synthesis and crystal structure of [(PhenH)(PhenH2)][BiCl6]·2H2O with different o-phenanthroline protonations. Journal of Chemical Crystallography 28, 791–796 (1998). https://doi.org/10.1023/A:1021871502627

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  • DOI: https://doi.org/10.1023/A:1021871502627

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