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Synthesis of Polycyclic Functionally-substituted Triazole- and Tetrazole-containing Systems

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Abstract

Cycloaddition of organic mono- and diazides to the triple bond of propargyl esters of mono- and dicarboxylic acids gave rise to polycyclic 1,2,3-triazole-substituted carboxylates. Dipropargyl dicarboxylates with diazides afforded oligomeric products with alternating triazole and carboxylate fragments. Reaction of a dipropargyl ester with 5-azidomethyltetrazole furnished a tetracyclic system with alternating triazole and tetrazole rings.

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REFERENCES

  1. Verkhozina, O.N., Kizhnyaev, V.N., Vereshchagin, L.I., Rokhin, A.V., and Smirnov, A.I., Zh. Org. Khim., 2003, vol. 39, p. 1863.

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  2. Rabeck, J. F., Experimental Methods in Polymer Chemistry, New York: John Wiley & Sons, 1980.

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Authors and Affiliations

  1. Institute of Petroleum and Coal-Processing at Irkutsk State University, Irkutsk, 664003, Russia

    L. I. Vereshchagin, V. N. Kizhnyaev, O. N. Verkhozina, A. G. Proidakov & A.I. Smirnov

Authors
  1. L. I. Vereshchagin
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  2. V. N. Kizhnyaev
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  3. O. N. Verkhozina
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  4. A. G. Proidakov
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  5. A.I. Smirnov
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Vereshchagin, L.I., Kizhnyaev, V.N., Verkhozina, O.N. et al. Synthesis of Polycyclic Functionally-substituted Triazole- and Tetrazole-containing Systems. Russian Journal of Organic Chemistry 40, 1156–1161 (2004). https://doi.org/10.1023/B:RUJO.0000045898.10072.7f

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  • DOI: https://doi.org/10.1023/B:RUJO.0000045898.10072.7f

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