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Improvement of Corrosion Resistance of Metals by an Environmentally Friendly Silica Coating Method

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Abstract

Corrosion resistance of stainless steel and Zn plated steel can be improved by a chromium-free environmentally friendly chemical solution deposition method. Precursor solutions were prepared from tetraethoxysilane with polymer, and were deposited on stainless steel, Zn plated steel and aluminum alloy by dip coating, followed by heat treatment. Addition of polymer to the precursor solution proved very effective in preparing films free from cracks on stainless steel and aluminum alloy substrates. The corrosion resistance was greatly improved by the resulting sub-micron thick silica-polymer hybrid film coatings on stainless steel and on Zn plated steel prepared at 200°C. The hardness of aluminum alloy coated with silica-PMMA hybrid film was improved by 7% over uncoated alloy.

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References

  1. A.R. de Arellano-López and K.T. Faber, J. Am. Ceram. Soc. 82, 2204 (1999).

    Google Scholar 

  2. K. An, K.S. Ravichandran, R.E. Dutton, and S.L. Semiatin, J. Am. Ceram. Soc. 82, 399 (1999).

    Google Scholar 

  3. O. de Sanctis, L. Gómez, N. Pellegri, C. Parodi, A. Marajofsky, and A. Durán, J. Non-Cryst. Solids 121, 338 (1990).

    Google Scholar 

  4. K. Izumi, H. Tanaka, M. Murakami, T. Deguchi, A. Morita, N. Tohge, and T. Minami, J. Non-Cryst. Solids 121, 344 (1990).

    Google Scholar 

  5. A.R. Di Giampaolo Conde, M. Puerta, H. Ruiz, and J. Lira Olivares, J. Non-Cryst. Solids 147/148, 467 (1992).

    Google Scholar 

  6. K. Izumi, H. Tanaka, Y. Uchida, N. Tohge, and T. Minami, J. Non-Cryst. Solids 147/148, 483 (1992).

    Google Scholar 

  7. M. Atik, J. Zarzycki, and C. R'kha, J. Mater. Sci. Lett. 13, 266 (1994).

    Google Scholar 

  8. M. Atik, C. R'kha, P. De Lima Neto, L. A. Avaca, M. A. Aegerter, and J. Zarzycki, J. Mater. Sci. Lett. 14, 178 (1995).

    Google Scholar 

  9. M.F.M. Zwinkels, S.G. Järås, P.G. Menon, and K.I. Åsen, J. Mater. Sci. 31, 6345 (1996).

    Google Scholar 

  10. S. Hirai, K. Shimakage, M. Sekiguchi, K. Wada, and A. Nukui, J. Am. Ceram. Soc. 82, 2011 (1999).

    Google Scholar 

  11. P.B. Kirk and R.M. Pillar, J. Mater. Sci. 34, 3967 (1999).

    Google Scholar 

  12. F. Perdomol L., P. De Lima-Neto, M.A. Aegerter, and L.A. Avaca, J. Sol-Gel Sci. Technol. 15, 87 (1999).

    Google Scholar 

  13. S.H. Messaddeq, S.H. Pulcinelli, C.V. Santilli, A.C. Guastaldi, and Y. Messaddeq, J. Non-Cryst. Solids 247, 164 (1999).

    Google Scholar 

  14. S. Ono, Y. Nishi, and S. Hirano, J. Am. Ceram. Soc. 84, 3054 (2001).

    Google Scholar 

  15. H. Tsuge, Y. Nishi, M. Kume, and S. Ono, J. Chem. Soc. Japan 12, 715 (2001).

    Google Scholar 

  16. S. Ono, H. Tsuge, Y. Matsuda, and K. Ogawa, J. Ceram. Soc. Japan 111, 698 (2003).

    Google Scholar 

  17. T.P. Chou, C. Chandrasekaran, and G.Z. Cao, J. Sol-Gel Sci. Technol. 26, 321 (2003).

    Google Scholar 

  18. T.P. Chou, C. Chandrasekaran, S.J. Limmer, S. Seraji, Y. Wu, M.J. Forbess, C. Nguyen, and G.Z. Cao, J. Non-Cryst. Solids 290, 153 (2001).

    Google Scholar 

  19. C.D. Wagner, W.M. Riggs, L.E. Davis, J.F. Moulder, and G.E. Muilenberg, Handbook of X-ray Photoelectron Spectroscopy (Perkin-Elmer Corporation, Minnesota, 1979), pp. 42, 52.

    Google Scholar 

  20. N. Ikeo, Y. Iijima, N. Niimura, M. Sigematsu, T. Tazawa, S. Matsumoto, K. Kojima, and Y. Nagasawa, Handbook of X-ray Photoelectron Spectroscopy (JEOL, Tokyo, Japan, 1991), p. 202.

    Google Scholar 

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Ono, S., Tsuge, H., Nishi, Y. et al. Improvement of Corrosion Resistance of Metals by an Environmentally Friendly Silica Coating Method. Journal of Sol-Gel Science and Technology 29, 147–153 (2004). https://doi.org/10.1023/B:JSST.0000023849.33761.86

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  • DOI: https://doi.org/10.1023/B:JSST.0000023849.33761.86

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