Abstract
A Wilkinson's complex-derived SiO2-tethered catalyst via an amine ligand is not only fairly effective and stable for cyclohexene hydroformylation under the milder conditions of 100°C and 28 bar of equimolar CO and H2 but also prevailing over the corresponding homogeneous catalyst. This catalyst has the advantage of resistance to rhodium leaching or/and high activity over homologous tethered catalysts via phosphine and thiol ligands.
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Huang, L., Kawi, S. An Active and Stable Wilkinson's Complex-Derived SiO2-Tethered Catalyst Via an Amine Ligand for Cyclohexene Hydroformylation. Catalysis Letters 92, 57–62 (2004). https://doi.org/10.1023/B:CATL.0000011087.58049.32
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DOI: https://doi.org/10.1023/B:CATL.0000011087.58049.32