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Synthesis, properties, and X-ray structure of [Cu(dpa)Cl2] (dpa = di-(2-picolyl)amine)

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Abstract

The mono(dpa)copper(II) complex [Cu(dpa)Cl2] (1) (dpa = di-(2-picolyl)amine) has been synthesized and structurally characterized. It crystallizes in the monoclinic system P21/n with a = 8.155(1), b = 12.560(1), c = 12.817(2) Å, β = 91.64(2)°, V = 1312.3(2) Å3, Z = 4. The copper atom is coordinated by three nitrogen atoms from the dpa ligand and two chlorides in a distorted square-pyramidal environment. Cyclic voltammetric data show that 1 undergoes the reversible one-electron oxidation to the Cu(III) and the reversible one-electron reduction to the Cu(I) state.

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References

  1. Young, M.J.; Wahnon, D.; Hynes, R.C.; Chin, J. J. Am. Chem. Soc. 1995, 117, 9441.

    Google Scholar 

  2. Whitener, G.D.; Hagadorn, J.R.; Arnold, J. J. Chem. Soc., Dalton Trans. 1999, 1249.

  3. Vigato, P.A.; Tamburini, S.; Fenton, D.E. Coord. Chem. Rev. 1990, 106, 25.

    Google Scholar 

  4. Pickart, L.; Goodwin, W.H.; Burgua, W.; Murphy, T.B.;Johnson, D.K. Biochem. Pharmacol. 1983, 32, 3868.

    Google Scholar 

  5. Johnson, D.K.; Murphy, T.B.; Rose, N.J.; Goodwin, W.H.; Pickart, L. Inorg. Chim. Acta 1982, 67, 159.

    Google Scholar 

  6. Chan, S.C.; Koh, L.L.; Leung, P.-H.; Ranford, J.D.; Sim, K.Y. Inorg. Chim. Acta 1995, 236, 101.

    Google Scholar 

  7. Tamboura, F.B.; Gaye, M.; Sall, A.S.; Barry, A.H.; Jouini, T. Inorg. Chem. Commun. 2002, 5, 235.

    Google Scholar 

  8. Colacio, E.; Ghazi, M.; Kivekas, R.; Klinga, M.; Lloret, F.; Moreno, J. M. Inorg. Chem. 2000, 39, 2770.

    Google Scholar 

  9. Yang, S.-P.; Long, L.-S.; Chen, X.-M.; Ji, L.-N. Acta Crystallogr. 1999, C55, 869.

    Google Scholar 

  10. Sheldrick, G.M. Acta Crystallogr. 1990, A46, 467.

    Google Scholar 

  11. Sheldrick, G.M. SHELXL-97, Program for the Refinement of Crystal Structures; University of Göttingen: Germany, 1997.

    Google Scholar 

  12. Addison, A.W.; Rao, T.N.; Reedijk, J.; van Rijn, J.; Verschoor, G.C. J. Chem. Soc., Dalton Trans. 1984, 1349.

  13. Bastida, R.; de Blas, A.; Castro, P.; Fenton, D.E.; Macias, A.; Rial, R.; Rodriguez, A.; Rodriguez-Blas, T. J. Chem. Soc., Dalton Trans. 1996, 1493.

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Authors and Affiliations

  1. Department of Chemistry Education, Kongju National University, Kongju, 314-701, Korea

    Ki-Young Choi & Haiil Ryu

  2. Division of Applied Biology and Chemistry, Research Center for Transgenic Cloned Pigs, Chungnam National University, Taejon, Korea

    Nack-Do Sung

  3. Department of Geoenvironmental Science, Kongju National University, Kongju, Korea

    Mancheol Suh

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  1. Ki-Young Choi
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  2. Haiil Ryu
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  3. Nack-Do Sung
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  4. Mancheol Suh
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Correspondence to Ki-Young Choi.

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Choi, KY., Ryu, H., Sung, ND. et al. Synthesis, properties, and X-ray structure of [Cu(dpa)Cl2] (dpa = di-(2-picolyl)amine). Journal of Chemical Crystallography 33, 947–950 (2003). https://doi.org/10.1023/A:1027485932736

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