Abstract
A new coordination polymer, catena-poly[Rh2(OAc)4(C27H15N3)]⋅2CH2Cl2 1 has been synthesized by self-assembly from Rh2(OAc)4 dimer units and the new ligand, 1,3,5-tris[(2-pyridyl)ethenyl]benzene 2. The compound was characterized by single crystal X-ray diffraction and was found to crystallize in the triclinic space group P-1, with a = 10.8206(9) Å, b = 14.0331(12) Å, c = 15.0901(12) Å, α = 113.965(2)°, β = 100.250(2)°, γ = 90.462(2)°, and Z = 2. The one-dimensional polymer contains two crystallographically different Rh-dimer units, both located about crystallographic inversion centers. Each Rh2(OAc)4 unit connects in a trans fashion with the potentially tridentate ligand giving an overall 1:1 metal dimer-to-ligand ratio. This arrangement leaves a third nitrogen donor site on the ligand uncoordinated.
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Amabilino, D.B.; Stoddart, J.F. Chem. Rev. 1995, 95, 2725.
Herrman, W.A.; Huver, N.W.; Runte, O. Angew. Chem. Int. Ed. Engl. 1995, 34, 2187.
Stein, A.; Keller, S.W.; Mallouk, T. E. Science 1993, 259, 1558.
Fujita, M.; Kwon, Y.J.; Washizu, S.; Ogura, K. J. Am. Chem. Soc. 1994, 116, 1151.
Lin, W.; Evans, O.R.; Xiong, R.-G.; Wang, Z. J. Am. Chem. Soc. 1998, 120, 13272.
Yaghi, O.M.; Li, H. J. Am. Chem. Soc. 1995, 117, 10401.
Yaghi, O.M.; Li, H.; Groy, T. L. J. Am. Chem. Soc. 1996, 118, 9096.
Gardner, G.B.; Venkataraman, D.; Moore, J.S.; Lee, S. Nature 1995, 374, 792.
Gardner, G.B.; Kianng, Y.-H.; Lee, S.; Asganokar, A.; Venkataraman, D. J. Am. Chem. Soc. 1996, 118, 6946.
Kahn, O.; Pei, Y.; Verdguer, M.; Renard, J.P.; Sletten, J. J. Am. Chem. Soc. 1988, 110, 782.
Valentine, J.S.; Silverstein, A. J.; Soos, Z.G. J. Am. Chem. Soc. 1974, 96, 97.
Lu, J.; Harrison, W.T.A.; Jacobson, A.J. Chem. Commun. 1996, 3, 399.
Batten, S.R.; Hoskins, B.F.; Moubaraki, B.; Murray, K.S.; Robson, R. Chem. Commun. 2000, 13, 1095.
Chandra, T.; Huffman, J.C.; Zaleski, J.M. Inorg. Chem. Com-mun. 2001, 4, 434.
Smith, G.; O'Reilly, E.J.; Carrell, H.L.; Carrell, C.J. Polyhedron 2001, 15, 1995.
Miyasaka, H.; Campos-Fernandez, C.S.; Galan-Mascaros, J.R.; Dunbar, K.R. Inorg. Chem. 2000, 39, 5870.
Miyasaka, H.; Clerac, R.; Campos-Fernandez, C.S.; Dunbar, K.R. J. Chem. Soc., Dalton Trans. 2001, 6, 858.
Chisholm, M.H. Acc. Chem. Res. 2000, 33, 53.
Cotton, F.A.; Lin, C.; Murillo, C.A. Acc. Chem. Res. 2001, 34, 759.
Chernyaev, I.; Shenderetskaya, E.; Karyagina, A. Russ. J. Inorg. Chem. 1960, 5, 559.
Cotton, F.A.; Felthouse, T.R. Inorg. Chem. 1981, 20, 2703.
Kim, Y.; Kim, S.-J.; Laugh, A. J. Polyhedron 2001, 20, 3073.
Fiscus, J.E.; Shotwell, S.; Smith, M.D.; Bunz, U.H.F.; zur Loye, H.-C. Chem. Commun. 2001, 24, 2674.
Pruchnik, F.P.; Robert, F.; Jeannin, Y.; Jeannin, S. Inorg. Chem. 1996, 35, 4261.
Cotton, F.A.; Kim, Y. J. Am. Chem. Soc. 1993, 115, 8511.
Kitamura, H.; Ozawa, T.; Jitsukawa, K.; Masuda, H.; Aoyama, Y.; Einaga, H. Inorg. Chem. 2000, 39, 3294.
Crawford, C.A.; Day, E.F.; Streib, W.E.; Huffman, J.C.; Chris-tou, G. Polyhedron 1994, 13, 2933.
Chapman, C.T.; Ciurtin, D.M.; Smith, M.D.; zur Loye, H.-C. Solid State Sci. 2002, 4, 1187.
SMART Version 5.619 and SAINT+ Version 6.02a; Bruker An-alytical X-ray Systems, Inc.: Madison, WI, 1998.
Sheldrick, G. M. SHELXTL Version 5.1; Bruker Analytical X-ray Systems, Inc.: Madison, WI, 1997.
Cotton, F.A.; Lin, C.; Murillo, C.A. J. Chem. Soc., Dalton Trans. 2001, 5, 499.
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Chapman, C.T., Goforth, A.M., Pschirer, N.G. et al. Synthesis and crystal structure of catena-poly[Rh2(OAc)4(C27H15N3)]⋅2CH2CL2, a novel Rh(II) organic/inorganic coordination polymer. Journal of Chemical Crystallography 33, 885–890 (2003). https://doi.org/10.1023/A:1027414030899
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DOI: https://doi.org/10.1023/A:1027414030899