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The Structure of the Pyridine Complex of p-tetrakis(phenylazo)-tetra-hydroxythiacalix[4]arene

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Abstract

p-Tetrakis(phenylazo)-tetra-hydroxythiacalix[4]arene shows complexing properties with neutral molecules. A complex with pyridine was crystallized and the crystal structure determined. The crystals are monoclinic, space group C2/c, a = 49.953(10), b = 21.566(4), c = 23.448(5) Å, β = 105.12(3)°, V = 24386(8) Å 3, Z = 16. Two macrocycles are positioned in such a way that they form a cavity where two pyridine molecules are encapsulated giving a 2:2 endocomplex. 5.5 other pyridine molecules are trapped between the macrocycles, two of them giving H-bonds with the calixarenes.

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Authors and Affiliations

  1. Laboratoire de Cristallographie, UMR CNRS 5078, Université Claude Bernard Lyon1, 43 Boulevard du, 69622, Villeurbanne cedex, France

    M. Perrin, C. Bavoux, F. Vocanson, R. Lamartine, C. Desroches, P. Miele & S. Parola

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  1. M. Perrin
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  2. C. Bavoux
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  3. F. Vocanson
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  4. R. Lamartine
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  5. C. Desroches
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  6. P. Miele
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  7. S. Parola
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Correspondence to M. Perrin.

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Perrin, M., Bavoux, C., Vocanson, F. et al. The Structure of the Pyridine Complex of p-tetrakis(phenylazo)-tetra-hydroxythiacalix[4]arene. Journal of Inclusion Phenomena 46, 15–17 (2003). https://doi.org/10.1023/A:1025656715493

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  • DOI: https://doi.org/10.1023/A:1025656715493

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