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Binuclear Cu(II) and Ni(II) Complexes with Schiff Bases—the Products of Condensation of Amino Alcohols with 2-Phenylhydrazone 1-Phenylbutane-1,2,3-Trione: Synthesis and Magnetic Properties

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Abstract

The binuclear complexes of Cu2+ and Ni2+ with a new ligand system obtained through condensation of amino alcohols with 2-phenylhydrazone 1-phenylbutane-1,2,3-trione were synthesized. The compositions and structures of ligands and complexes were determined using elemental analysis, IR and NMR spectroscopy and magnetochemistry. The nickel complexes were found to be diamagnetic; in the copper complexes, substantial antiferromagnetic exchange interaction was observed (for Cu2+ complexes with n = 2 and 3, 2J is equal to –396 and –393 cm–1, respectively). The structure of the exchange fragment \(O \backslash / Cu Cu O \backslash /\) is discussed.

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References

  1. Kogan, V.A., Zelentsov, V.V., Larin, G.M., and Lukov, V.V., Kompleksy perekhodnykh metallov s gidrazonami: Fiziko-khimicheskie svoistva i stroenie (Complexes of Transition Metals with Hydrazones: Physicochemical Properties and Structure), Moscow: Nauka, 1990.

    Google Scholar 

  2. Kurbatov, V.P., Antsyshkina, A.S., Kukharicheva, E.S., and Garnovskii, A.D., Zh. Neorg. Khim., 1996, vol. 41, no. 8, p. 1315.

    Google Scholar 

  3. Kurbatov, V.P., Kukharicheva, E.S., and Vysotskii, B.D., Zh. Neorg. Khim., 1997, vol. 42, no. 6, p. 996.

    Google Scholar 

  4. Garnovskii, A.D., Kochin, S.G., Vasil'chenko, I.S., et al., Zh. Obshch. Khim., 1989, vol. 59, no. 12, p. 2797.

    Google Scholar 

  5. Garnovskii, A.D., Mistryukov, A.E., Bren', V.A., et al., Zh. Neorg. Khim., 1992, vol. 37, no. 7, p. 1513.

    Google Scholar 

  6. Garnovskii, A.D., Vasil'chenko, I.S., Mistryukov, A.E., et al., Zh. Obshch. Khim., 1993, vol. 63, no. 5, p. 1144.

    Google Scholar 

  7. Kalinnikov, V.T. and Rakitin, Yu.V., Vvedenie v magnetokhimiyu (Introduction to Magnetochemistry), Moscow: Nauka, 1990.

    Google Scholar 

  8. Rakitin, Yu.V., Itogi Nauki Tekh., Ser. Str. Mol. Khim. Svyaz', Moscow: VINITI, 1986, p. 95.

    Google Scholar 

  9. Lukov, V.V., Doctoral (Chem.) Dissertation, Rostov-on-Don: Rostov State Univ., 2000.

  10. Potapov, V.M., Panova, G.V., and Turovets, I.M., Zh. Obshch. Khim., 1984, vol. 54, no. 5, p. 1185.

    Google Scholar 

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  1. Rostov State University, pr. Stachki 194/3, Rostov-on-Don, 344104, Russia

    E. V. Dontsova, V. V. Lukov, V. A. Kogan & L. D. Popov

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  1. E. V. Dontsova
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  2. V. V. Lukov
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  3. V. A. Kogan
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  4. L. D. Popov
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Dontsova, E.V., Lukov, V.V., Kogan, V.A. et al. Binuclear Cu(II) and Ni(II) Complexes with Schiff Bases—the Products of Condensation of Amino Alcohols with 2-Phenylhydrazone 1-Phenylbutane-1,2,3-Trione: Synthesis and Magnetic Properties. Russian Journal of Coordination Chemistry 29, 639–642 (2003). https://doi.org/10.1023/A:1025611727728

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