Skip to main content
Log in

Preparation and Properties of Polycrystalline ZnS for IR Applications

  • Published:
Inorganic Materials Aims and scope

Abstract

Data are summarized on the optical and mechanical properties of polycrystalline ZnS prepared by different methods. Particular attention is paid to the effect of impurities on the properties of ZnS and the optimization of its performance parameters for IR optical applications.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

REFERENCES

  1. Morozova, N.K. and Kuznetsov, V.A., Sul'fid tsinka (Zinc Sulfide), Moscow: Nauka, 1987, p. 200.

    Google Scholar 

  2. Karpova, A.P., Belyaeva, A.I., and Komar', V.K., Far-IR Transmission of Zinc Sulfide Crystals at Low Temperatures, VII Vsesoyuznoe soveshchanie po kristallicheskim opticheskim materialam (VII All-Union Conf. on Crystalline Optical Materials), Leningrad, 1989, pp. 74-75.

  3. Voskresenskaya, V.I., Mozhaiskaya, V.S., and Nikolaeva, S.V., Interference Study of Optical Homogeneity of Polycrystalline Zinc and Cadmium Chalcogenides, VII Vsesoyuznoe soveshchanie po kristallicheskim opticheskim materialam (VII All-Union Conf. on Crystalline Optical Materials), Leningrad, 1989, pp. 67-68.

  4. Petrovsky, G.T., Optical Materials for Infrared Range of Spectrum, Proc. SPIE-Int. Soc. Opt. Eng., 1991, vol. 1540, pp. 401-411.

    Google Scholar 

  5. Shibata, K., EEC Patent 0950904 A1, 1999.

  6. Donadio, R.N., Connolly, J.F., and Taylor, R.L., New Advances in Chemical Vapor Deposited (CVD) Infrared Transmitting Materials, Proc. SPIE-Int. Soc. Opt. Eng., 1981, vol. 297, pp. 65-69.

    Google Scholar 

  7. Harris, R.L., Graves, G.A., Dempsey, D.V., et al., Optical and Mechanical Properties of Water Clear ZnS, NBS Spec. Publ., 1984, vol. 686, pp. 52-58.

    Google Scholar 

  8. Goela, J.S., US Patent 6221482, 2001.

  9. Goela, J.S. and Salihbegovic, Z., US Patent 6083561, 2000.

  10. Taylor, R.L. and Donadio, R.N., An Infrared Alternative: Vapor Deposited Materials, Laser Focus, 1981, vol. 17, no. 7, pp. 41-43.

    Google Scholar 

  11. Braudeau, Ph., Keller, G., and Torre, J.P., CVD of IRTransmitting ZnS, J. Phys., Colloq., 1986, vol. 47, pp. 1–193-1-196.

    Google Scholar 

  12. Anan'eva, G.V. and Gorokhova, E.I., Optical Transmission and Structure of Polycrystalline Zinc Sulfide, Opt. Zh., 1997, vol. 64, no. 9, pp. 75-77.

  13. Mochizuki, K., Vapor Growth and Polarity on ZnS Crystals, J. Cryst. Growth, 1985, vol. 71, pp. 459-462.

    Google Scholar 

  14. Russel, G.J. and Woods, J., Vapor Growth and Defect Characterization of Large Crystals of ZnS and Zn(S,Se), J. Cryst. Growth, 1979, vol. 47, pp. 647-653.

    Google Scholar 

  15. Hartmann, H., Growth of ZnS Single Crystals from the Vapor Phase, Phys. Status Solidi, 1962, vol. 2, pp. 585-589.

    Google Scholar 

  16. Shibata, K., US Patent 6111689, 2000.

  17. Kozelsky, M.J., Growth of ZnS Single Crystals from the Melt, J. Cryst. Growth, 1967, vol. 1, no. 5, pp. 293-296.

    Google Scholar 

  18. Green, L.C., Reynolds, D.C., Cryzac, S.J., and Baker, W.M., Melt Grown ZnS Single Crystal, J. Chem. Phys., 1958, vol. 29, pp. 1375-1377.

    Google Scholar 

  19. Kuznetsov, V.A., Melt-Grown Zinc Sulfide Crystals, Rost Krist., 1964, pp. 144-147.

  20. Anan'eva, G.V., Structure of ZnS Crystals Grown from the Melt under Pressure, Fiz. Tverd. Tela (Leningrad), 1968, vol. 10, no. 6, pp. 1800-1806.

  21. Sharmann, A. and Schwabe, D., Distribution Coefficient of Transition Metal and Lead and Tin in Melt-Growth ZnS Crystals, J. Cryst. Growth, 1977, vol. 38, no. 1, pp. 8-12.

    Google Scholar 

  22. Liang A. Xue and Rishi Raj, Effect of Hot-Pressing Temperature on the Optical Transmission of Zinc Sulfide, Appl. Phys. Lett., 1991, vol. 58, no. 5, pp. 441-443.

    Google Scholar 

  23. Bohren, C. and Huffman, D., Absorption and Scattering of Light by Small Particles, New York: Wiley, 1983. Translated under the title Pogloshchenie i rasseyanie sveta malymi chastitsami, Moscow: Mir, 1986.

    Google Scholar 

  24. Savage, J.A., The Role of CVD Research Reactor in Studies of the Growth and Physical Properties of ZnS Infrared Optical Material, Proc. SPIE-Int. Soc. Opt. Eng., 1984, vol. 505, pp. 47-51.

    Google Scholar 

  25. Devyatykh, G.G., Gavrishchuk, E.M., and Yashina, E.V., Effect of Deposition Conditions on the Microstructure of CVD ZnS, Neorg. Mater., 1996, vol. 32, no. 6, pp. 667-669 [Inorg. Mater. (Engl. Transl.), vol. 32, no. 6, pp. 589-591].

    Google Scholar 

  26. Anan'eva, G.V. and Gorokhova, E.I., Effect of High-Temperature Deformation Conditions on the Structure and Properties of ZnS, Opt. Zh., 1997, vol. 64, no. 12, pp. 52-55.

  27. Savushkin, V.N., Mironov, I.A., Volynskaya, S.M., et al., Physicomechanical and Structural Properties of Zinc Sulfide Polycrystals Prepared by Different Techniques, Opt. Zh., 1992, no. 7, pp. 53-57.

    Google Scholar 

  28. Klein, C.A., di Benedetto, B., and Pappis, J., ZnS, ZnSe, and ZnS/ZnSe Windows: Their Impact on FLIR System Performance, Opt. Eng. (Bellingham, Wash.), 1986, vol. 25, no. 4, pp. 519-531.

    Google Scholar 

  29. Willingham, Ch.B. and Pappis, J., US Patent 4944900, 1990.

  30. Dronova, G.N., Loginov, F.N., and Nikolaeva, S.V., Effect of Doping Impurities on Zinc Sulfide CVD, VII Vsesoyuznoe soveshchanie po kristallicheskim opticheskim materialam (VII All-Union Conf. on Crystalline Optical Materials), Leningrad, 1989, pp. 38-39.

  31. Smirnaya, E.P., Bezruk, E.T., Yushkevich, E.E., and Shlyavas, T.L., Effects of Heat Treatment and Doping on the Optical and Mechanical Properties of Zinc Sulfide, VII Vsesoyuznoe soveshchanie po kristallicheskim opticheskim materialam (VII All-Union Conf. on Crystalline Optical Materials), Leningrad, 1989, pp. 87-88.

  32. Harris, N.H., EEC Patent 0678760 A1, 1995.

  33. Wahl, J.A., Wong, T.Y., and Tustison, R.W., EEC Patent 0486236 B1, 1991.

  34. Willingham, Ch.B. and Pappis, J., UK Patent 2125023 A, 1984.

  35. Uematsu, K., Sawada, K., Kato, Z., et al., Effect of Additives on the Hot Pressing of Zinc Sulfide, J. Mater. Sci. Lett., 1988, vol. 7, no. 5, p. 473.

  36. Liang, A.X. and Rishi, R., Grain Growth in Superplastically Deformed Zinc Sulfide/Diamond Composites, J. Am. Ceram. Soc., 1991, vol. 74, no. 7, pp. 1729-1731.

    Google Scholar 

  37. Devyatykh, G.G., Gavrishchuk, E.M., Fatenkov, A.N., and Yashina, E.V., The Effect of CVD Conditions on the Porosity of Zinc Sulfide, Neorg. Mater., 1995, vol. 31, no. 8, pp. 1017-1019 [Inorg. Mater. (Engl. Transl.), vol. 31, no. 8, pp. 936-938].

    Google Scholar 

  38. Lewis, K.L., Cook, D.J., and Roscoe, P.B., The Structure and Optical Properties of Polycrystalline ZnSxSe1 - x Prepared by Chemical Vapor Deposition, J. Cryst. Growth, 1982, vol. 56, pp. 614-620.

    Google Scholar 

  39. Lewis, K.L., Arthur, G.S., and Edwards, D.A., The Incorporation of Iron Impurities in Cubic ZnS, J. Cryst. Growth, 1982, vol. 52, pp. 201-209.

    Google Scholar 

  40. Lewis, K.L., Hydrogen-Related Defects in Vapor Deposited ZnS, J. Cryst. Growth, 1984, vol. 66, pp. 125-136.

    Google Scholar 

  41. Goela, J.S. and Taylor, R.L., Monolithic Material Fabrication by Chemical Vapor Deposition, J. Mater. Sci., 1988, vol. 23, pp. 4331-4339.

    Google Scholar 

  42. Nisenholz, Z., Paz, M., Hefetz, M., et al., Windows for Infra-Red & Visible Light Produced by Chemical Vapor Deposition of ZnS, Isr. J. Technol., 1988, vol. 24, pp. 627-632.

    Google Scholar 

  43. Miels, P., High Transparency Infrared Materials-a Technology Update, Opt. Eng. (Bellingham, Wash.), 1976, vol. 15, no. 5, pp. 151-159.

    Google Scholar 

  44. Campbell, A. and Hayman, C., Manufacturing Aspects of Zinc Sulfide, SPIE Res. Develop. IR Compd., 1988, vol. 915, pp. 79-83.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Yashina, E.V. Preparation and Properties of Polycrystalline ZnS for IR Applications. Inorganic Materials 39, 663–668 (2003). https://doi.org/10.1023/A:1024567204605

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1024567204605

Keywords

Navigation