Abstract
Data are summarized on the optical and mechanical properties of polycrystalline ZnS prepared by different methods. Particular attention is paid to the effect of impurities on the properties of ZnS and the optimization of its performance parameters for IR optical applications.
Similar content being viewed by others
REFERENCES
Morozova, N.K. and Kuznetsov, V.A., Sul'fid tsinka (Zinc Sulfide), Moscow: Nauka, 1987, p. 200.
Karpova, A.P., Belyaeva, A.I., and Komar', V.K., Far-IR Transmission of Zinc Sulfide Crystals at Low Temperatures, VII Vsesoyuznoe soveshchanie po kristallicheskim opticheskim materialam (VII All-Union Conf. on Crystalline Optical Materials), Leningrad, 1989, pp. 74-75.
Voskresenskaya, V.I., Mozhaiskaya, V.S., and Nikolaeva, S.V., Interference Study of Optical Homogeneity of Polycrystalline Zinc and Cadmium Chalcogenides, VII Vsesoyuznoe soveshchanie po kristallicheskim opticheskim materialam (VII All-Union Conf. on Crystalline Optical Materials), Leningrad, 1989, pp. 67-68.
Petrovsky, G.T., Optical Materials for Infrared Range of Spectrum, Proc. SPIE-Int. Soc. Opt. Eng., 1991, vol. 1540, pp. 401-411.
Shibata, K., EEC Patent 0950904 A1, 1999.
Donadio, R.N., Connolly, J.F., and Taylor, R.L., New Advances in Chemical Vapor Deposited (CVD) Infrared Transmitting Materials, Proc. SPIE-Int. Soc. Opt. Eng., 1981, vol. 297, pp. 65-69.
Harris, R.L., Graves, G.A., Dempsey, D.V., et al., Optical and Mechanical Properties of Water Clear ZnS, NBS Spec. Publ., 1984, vol. 686, pp. 52-58.
Goela, J.S., US Patent 6221482, 2001.
Goela, J.S. and Salihbegovic, Z., US Patent 6083561, 2000.
Taylor, R.L. and Donadio, R.N., An Infrared Alternative: Vapor Deposited Materials, Laser Focus, 1981, vol. 17, no. 7, pp. 41-43.
Braudeau, Ph., Keller, G., and Torre, J.P., CVD of IRTransmitting ZnS, J. Phys., Colloq., 1986, vol. 47, pp. 1–193-1-196.
Anan'eva, G.V. and Gorokhova, E.I., Optical Transmission and Structure of Polycrystalline Zinc Sulfide, Opt. Zh., 1997, vol. 64, no. 9, pp. 75-77.
Mochizuki, K., Vapor Growth and Polarity on ZnS Crystals, J. Cryst. Growth, 1985, vol. 71, pp. 459-462.
Russel, G.J. and Woods, J., Vapor Growth and Defect Characterization of Large Crystals of ZnS and Zn(S,Se), J. Cryst. Growth, 1979, vol. 47, pp. 647-653.
Hartmann, H., Growth of ZnS Single Crystals from the Vapor Phase, Phys. Status Solidi, 1962, vol. 2, pp. 585-589.
Shibata, K., US Patent 6111689, 2000.
Kozelsky, M.J., Growth of ZnS Single Crystals from the Melt, J. Cryst. Growth, 1967, vol. 1, no. 5, pp. 293-296.
Green, L.C., Reynolds, D.C., Cryzac, S.J., and Baker, W.M., Melt Grown ZnS Single Crystal, J. Chem. Phys., 1958, vol. 29, pp. 1375-1377.
Kuznetsov, V.A., Melt-Grown Zinc Sulfide Crystals, Rost Krist., 1964, pp. 144-147.
Anan'eva, G.V., Structure of ZnS Crystals Grown from the Melt under Pressure, Fiz. Tverd. Tela (Leningrad), 1968, vol. 10, no. 6, pp. 1800-1806.
Sharmann, A. and Schwabe, D., Distribution Coefficient of Transition Metal and Lead and Tin in Melt-Growth ZnS Crystals, J. Cryst. Growth, 1977, vol. 38, no. 1, pp. 8-12.
Liang A. Xue and Rishi Raj, Effect of Hot-Pressing Temperature on the Optical Transmission of Zinc Sulfide, Appl. Phys. Lett., 1991, vol. 58, no. 5, pp. 441-443.
Bohren, C. and Huffman, D., Absorption and Scattering of Light by Small Particles, New York: Wiley, 1983. Translated under the title Pogloshchenie i rasseyanie sveta malymi chastitsami, Moscow: Mir, 1986.
Savage, J.A., The Role of CVD Research Reactor in Studies of the Growth and Physical Properties of ZnS Infrared Optical Material, Proc. SPIE-Int. Soc. Opt. Eng., 1984, vol. 505, pp. 47-51.
Devyatykh, G.G., Gavrishchuk, E.M., and Yashina, E.V., Effect of Deposition Conditions on the Microstructure of CVD ZnS, Neorg. Mater., 1996, vol. 32, no. 6, pp. 667-669 [Inorg. Mater. (Engl. Transl.), vol. 32, no. 6, pp. 589-591].
Anan'eva, G.V. and Gorokhova, E.I., Effect of High-Temperature Deformation Conditions on the Structure and Properties of ZnS, Opt. Zh., 1997, vol. 64, no. 12, pp. 52-55.
Savushkin, V.N., Mironov, I.A., Volynskaya, S.M., et al., Physicomechanical and Structural Properties of Zinc Sulfide Polycrystals Prepared by Different Techniques, Opt. Zh., 1992, no. 7, pp. 53-57.
Klein, C.A., di Benedetto, B., and Pappis, J., ZnS, ZnSe, and ZnS/ZnSe Windows: Their Impact on FLIR System Performance, Opt. Eng. (Bellingham, Wash.), 1986, vol. 25, no. 4, pp. 519-531.
Willingham, Ch.B. and Pappis, J., US Patent 4944900, 1990.
Dronova, G.N., Loginov, F.N., and Nikolaeva, S.V., Effect of Doping Impurities on Zinc Sulfide CVD, VII Vsesoyuznoe soveshchanie po kristallicheskim opticheskim materialam (VII All-Union Conf. on Crystalline Optical Materials), Leningrad, 1989, pp. 38-39.
Smirnaya, E.P., Bezruk, E.T., Yushkevich, E.E., and Shlyavas, T.L., Effects of Heat Treatment and Doping on the Optical and Mechanical Properties of Zinc Sulfide, VII Vsesoyuznoe soveshchanie po kristallicheskim opticheskim materialam (VII All-Union Conf. on Crystalline Optical Materials), Leningrad, 1989, pp. 87-88.
Harris, N.H., EEC Patent 0678760 A1, 1995.
Wahl, J.A., Wong, T.Y., and Tustison, R.W., EEC Patent 0486236 B1, 1991.
Willingham, Ch.B. and Pappis, J., UK Patent 2125023 A, 1984.
Uematsu, K., Sawada, K., Kato, Z., et al., Effect of Additives on the Hot Pressing of Zinc Sulfide, J. Mater. Sci. Lett., 1988, vol. 7, no. 5, p. 473.
Liang, A.X. and Rishi, R., Grain Growth in Superplastically Deformed Zinc Sulfide/Diamond Composites, J. Am. Ceram. Soc., 1991, vol. 74, no. 7, pp. 1729-1731.
Devyatykh, G.G., Gavrishchuk, E.M., Fatenkov, A.N., and Yashina, E.V., The Effect of CVD Conditions on the Porosity of Zinc Sulfide, Neorg. Mater., 1995, vol. 31, no. 8, pp. 1017-1019 [Inorg. Mater. (Engl. Transl.), vol. 31, no. 8, pp. 936-938].
Lewis, K.L., Cook, D.J., and Roscoe, P.B., The Structure and Optical Properties of Polycrystalline ZnSxSe1 - x Prepared by Chemical Vapor Deposition, J. Cryst. Growth, 1982, vol. 56, pp. 614-620.
Lewis, K.L., Arthur, G.S., and Edwards, D.A., The Incorporation of Iron Impurities in Cubic ZnS, J. Cryst. Growth, 1982, vol. 52, pp. 201-209.
Lewis, K.L., Hydrogen-Related Defects in Vapor Deposited ZnS, J. Cryst. Growth, 1984, vol. 66, pp. 125-136.
Goela, J.S. and Taylor, R.L., Monolithic Material Fabrication by Chemical Vapor Deposition, J. Mater. Sci., 1988, vol. 23, pp. 4331-4339.
Nisenholz, Z., Paz, M., Hefetz, M., et al., Windows for Infra-Red & Visible Light Produced by Chemical Vapor Deposition of ZnS, Isr. J. Technol., 1988, vol. 24, pp. 627-632.
Miels, P., High Transparency Infrared Materials-a Technology Update, Opt. Eng. (Bellingham, Wash.), 1976, vol. 15, no. 5, pp. 151-159.
Campbell, A. and Hayman, C., Manufacturing Aspects of Zinc Sulfide, SPIE Res. Develop. IR Compd., 1988, vol. 915, pp. 79-83.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Yashina, E.V. Preparation and Properties of Polycrystalline ZnS for IR Applications. Inorganic Materials 39, 663–668 (2003). https://doi.org/10.1023/A:1024567204605
Issue Date:
DOI: https://doi.org/10.1023/A:1024567204605