Skip to main content
Log in

Characterization and adsorption properties of powders prepared from cactus pulp

  • Published:
Journal of Materials Science Aims and scope Submit manuscript

Abstract

Two cactaceous powders, labelled CACMM1 and CACMM2, are shown to contain calcium oxalate and to consist of globular or cubosome particles. The samples were characterized by X-ray diffractometry, spectroscopic, thermic, nitrogen and water adsorption methods and compared with other organic compounds. The pore systems have been analysed from adsorption isotherms, t-plots and pore size distribution curves. The bioadsorbents CACMM1 and CACMM2 exhibited low specific surface area values and presented pores in the mesopore range. Composite adsorption isotherms for the binary mixtures benzene-hexane and benzene-cyclohexane on cactaceous powders have been established and revealed preferential adsorption of hexane and cyclohexane in the respective system. Also the adsorption behavior of dyes from aqueous solution was studied to complete the diversity of adsorbate molecules. Linear adsorption isotherms were obtained up to 6 mM dye equilibrium concentration.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. J. Mrowiec-BiaŁoŃ, A. B. Jarzecbski, A. I. Lachowski, J. J. Malinowski and Y. I. Aristov, Chem. Mater. 9 (1997) 2486.

    Google Scholar 

  2. H. D. Gesser and P. C Goswami, Chem. Rev. 89 (1989) 765.

    Google Scholar 

  3. M. M. DÁvila, M. P. Elizalde, M. GonzÁlez and E. GarcÍa, J. Electrochem. Soc. 144 (1997) 263.

    Google Scholar 

  4. M. Schneider and A. Baiker, Catal. Rev.-Sci. Eng. 37 (1995) 515.

    Google Scholar 

  5. Q. Huo, J. Feng, F. SchÜth and G. D. Stucky, Chem. Mater. 9 (1997) 14.

    Google Scholar 

  6. L. C. Morais, O. M. Freitas, E. P. Goncalves, L. T. Vasconcelos and C. G. Gonz Ález Beca, Wat. Res. 33 (1999) 979.

    Google Scholar 

  7. S. E. Bailey, T. J. Olin, R. M. Bricka and D. D. Adrian, ibid. 33 (1999) 2469.

    Google Scholar 

  8. S. Al-Asheh and Z. Duvnjak, Sep. Sci. Technol. 33 (1998) 1303.

    Google Scholar 

  9. G. Sun and W. Shi, Ind. Eng. Chem. Res. 37 (1998) 1324.

    Google Scholar 

  10. M. Ajmal, R. A. K. Rao and B. A. Siddiqui, Wat. Res. 30 (1996) 1478.

    Google Scholar 

  11. V. K. Gupta, D. Mohan and S. Sharma, Sep. Sci. Technol. 33 (1998) 1331.

    Google Scholar 

  12. N. Khalid, P. O. Nilore, S. Ahmad, S. N. Kiani and J. Ahmed, ibid. 33 (1998) 2349.

    Google Scholar 

  13. J. H. Forkner, U.S. Pat. 4,042,720, 1977.

  14. F. R. Kunkel, U.S. Pat. 5,000,857, 1991.

  15. M. M. DÁvila-Jim00e9;nez, M. P. ElizaldegonzÁlez, A. A. PelÁez-Cid and A. RosasjuÁrez, J. Mater. Sci. Lett. 16 (1997) 1145.

    Google Scholar 

  16. M. P. Elizalde-GonzÁlez and R. RuÍz-Palma, J. Chromatogr. 845 (1999) 373.

    Google Scholar 

  17. G. Carrillo-Morales, M. M. DÁvila-JimÉnez, M. P. Elizalde-GonzÁlez and A. A. PelÁez-Cid, J. Chromatogr. 938 (2001) 237.

    Google Scholar 

  18. M. M. DÁvila and M. P. Elizalde, Pat. Appl. Mex. No. 041412, 1997.

  19. A. L. VÁzquez-DÍaz, thesis, Universidad Autónoma de Puebla, México (1999).

    Google Scholar 

  20. A. V. Kiselev and V. P. Dreving, in “Eksperimental'nye metody v adsorbtsii i molekulyarnoi khromatografii” (Moscow Univ. Press, Moscow, 1973) p. 382.

    Google Scholar 

  21. N. V. Kel'tsev in “Teoreticheskie Osnovy Adsorbtionnoi Tekhniki” (Khimiya, Moscow, 1976) p. 511.

    Google Scholar 

  22. JCPDS ICDD, 1991.

  23. G. E. Domburg, V. N. Sergeeva and A. I. Kalninsh, in “Thermal analysis,” edited by H. G. Wiedemann Proceedings Third ICTA, Vol. 3 (Birkhäuser Verlag, Basel, 1972) p. 327.

    Google Scholar 

  24. K. V. Sarkanen, C. H. Ludwig, in “Lignins. Occurrence, Formation, Structure and Reactions”(Wiley Interscience, NewYork, 1971) p. 272.

    Google Scholar 

  25. V. Ya. Davydov, A. V. Kiselev and L. T. Zhuravlev, Trans. Faraday Soc. 60 (1964) 2254.

    Google Scholar 

  26. S. J. Gregg and K. S. W. Sing, in “Adsorption, Surface Area and Porosity” (Academic Press, London, 1982) p. 310.

    Google Scholar 

  27. J. Hayashi, T. Shoji, Y. Watada and K. Muroyama, Langmuir 13 (1997) 4185.

    Google Scholar 

  28. F. Rouquerol, J. Rouquerol and K. Sing, in “Adsorption by Powders &; Porous Solids” (AcademicPress, London, 1999) p. 467.

    Google Scholar 

  29. D. P. Valenzuela and A. L. Myers in “Adsorption Equilibrium Data Handbook” (Prentice Hall, New Jersey, 1989) p. 364.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to M. P. Elizalde-González.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Corro-Hernández, G., Elizalde-González, M.P. & Dávila-Jiménez, M.M. Characterization and adsorption properties of powders prepared from cactus pulp. Journal of Materials Science 38, 1339–1346 (2003). https://doi.org/10.1023/A:1022815416715

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1022815416715

Keywords

Navigation