Abstract
Two cactaceous powders, labelled CACMM1 and CACMM2, are shown to contain calcium oxalate and to consist of globular or cubosome particles. The samples were characterized by X-ray diffractometry, spectroscopic, thermic, nitrogen and water adsorption methods and compared with other organic compounds. The pore systems have been analysed from adsorption isotherms, t-plots and pore size distribution curves. The bioadsorbents CACMM1 and CACMM2 exhibited low specific surface area values and presented pores in the mesopore range. Composite adsorption isotherms for the binary mixtures benzene-hexane and benzene-cyclohexane on cactaceous powders have been established and revealed preferential adsorption of hexane and cyclohexane in the respective system. Also the adsorption behavior of dyes from aqueous solution was studied to complete the diversity of adsorbate molecules. Linear adsorption isotherms were obtained up to 6 mM dye equilibrium concentration.
Similar content being viewed by others
References
J. Mrowiec-BiaŁoŃ, A. B. Jarzecbski, A. I. Lachowski, J. J. Malinowski and Y. I. Aristov, Chem. Mater. 9 (1997) 2486.
H. D. Gesser and P. C Goswami, Chem. Rev. 89 (1989) 765.
M. M. DÁvila, M. P. Elizalde, M. GonzÁlez and E. GarcÍa, J. Electrochem. Soc. 144 (1997) 263.
M. Schneider and A. Baiker, Catal. Rev.-Sci. Eng. 37 (1995) 515.
Q. Huo, J. Feng, F. SchÜth and G. D. Stucky, Chem. Mater. 9 (1997) 14.
L. C. Morais, O. M. Freitas, E. P. Goncalves, L. T. Vasconcelos and C. G. Gonz Ález Beca, Wat. Res. 33 (1999) 979.
S. E. Bailey, T. J. Olin, R. M. Bricka and D. D. Adrian, ibid. 33 (1999) 2469.
S. Al-Asheh and Z. Duvnjak, Sep. Sci. Technol. 33 (1998) 1303.
G. Sun and W. Shi, Ind. Eng. Chem. Res. 37 (1998) 1324.
M. Ajmal, R. A. K. Rao and B. A. Siddiqui, Wat. Res. 30 (1996) 1478.
V. K. Gupta, D. Mohan and S. Sharma, Sep. Sci. Technol. 33 (1998) 1331.
N. Khalid, P. O. Nilore, S. Ahmad, S. N. Kiani and J. Ahmed, ibid. 33 (1998) 2349.
J. H. Forkner, U.S. Pat. 4,042,720, 1977.
F. R. Kunkel, U.S. Pat. 5,000,857, 1991.
M. M. DÁvila-Jim00e9;nez, M. P. ElizaldegonzÁlez, A. A. PelÁez-Cid and A. RosasjuÁrez, J. Mater. Sci. Lett. 16 (1997) 1145.
M. P. Elizalde-GonzÁlez and R. RuÍz-Palma, J. Chromatogr. 845 (1999) 373.
G. Carrillo-Morales, M. M. DÁvila-JimÉnez, M. P. Elizalde-GonzÁlez and A. A. PelÁez-Cid, J. Chromatogr. 938 (2001) 237.
M. M. DÁvila and M. P. Elizalde, Pat. Appl. Mex. No. 041412, 1997.
A. L. VÁzquez-DÍaz, thesis, Universidad Autónoma de Puebla, México (1999).
A. V. Kiselev and V. P. Dreving, in “Eksperimental'nye metody v adsorbtsii i molekulyarnoi khromatografii” (Moscow Univ. Press, Moscow, 1973) p. 382.
N. V. Kel'tsev in “Teoreticheskie Osnovy Adsorbtionnoi Tekhniki” (Khimiya, Moscow, 1976) p. 511.
JCPDS ICDD, 1991.
G. E. Domburg, V. N. Sergeeva and A. I. Kalninsh, in “Thermal analysis,” edited by H. G. Wiedemann Proceedings Third ICTA, Vol. 3 (Birkhäuser Verlag, Basel, 1972) p. 327.
K. V. Sarkanen, C. H. Ludwig, in “Lignins. Occurrence, Formation, Structure and Reactions”(Wiley Interscience, NewYork, 1971) p. 272.
V. Ya. Davydov, A. V. Kiselev and L. T. Zhuravlev, Trans. Faraday Soc. 60 (1964) 2254.
S. J. Gregg and K. S. W. Sing, in “Adsorption, Surface Area and Porosity” (Academic Press, London, 1982) p. 310.
J. Hayashi, T. Shoji, Y. Watada and K. Muroyama, Langmuir 13 (1997) 4185.
F. Rouquerol, J. Rouquerol and K. Sing, in “Adsorption by Powders &; Porous Solids” (AcademicPress, London, 1999) p. 467.
D. P. Valenzuela and A. L. Myers in “Adsorption Equilibrium Data Handbook” (Prentice Hall, New Jersey, 1989) p. 364.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Corro-Hernández, G., Elizalde-González, M.P. & Dávila-Jiménez, M.M. Characterization and adsorption properties of powders prepared from cactus pulp. Journal of Materials Science 38, 1339–1346 (2003). https://doi.org/10.1023/A:1022815416715
Issue Date:
DOI: https://doi.org/10.1023/A:1022815416715